1-(Phenylamino)pseudo-mauveine: a new water soluble phenazine dye

M. John Plater; Toby Jackson

doi:10.3184/174751914X14033559668812

1-(Phenylamino)pseudo-mauveine: a new water soluble phenazine dye

M. John Plater
, Toby Jackson

Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

9 Downloads (Pure)

Abstract

1-(Phenylamino)pseudo-mauveine was prepared by the oxidation of 1,3,5-tris(phenylamino)benzene and p-phenylenediamine with potassium dichromate. The absorption maximum of 535 nm is shifted hypsochromically by about 20 nm compared to that for pseudo-mauveine. Condensation of 1,3,5-tris(phenylamino)benzene with 4-nitrosodiphenylamine under strongly acidic conditions gave 1,3,7-tris(phenylamino)-5-phenylphenazinium sulfate and 10-phenyl-6,8-bis(phenylamino)-2,10-dihydrophenazin-2-one.

Original language	English
Pages (from-to)	437-442
Number of pages	6
Journal	Journal of Chemical Research
Volume	38
Issue number	7
DOIs	https://doi.org/10.3184/174751914X14033559668812
Publication status	Published - 1 Jul 2014

Keywords

1,3,5-TRIS(PHENYLAMINO)BENZENE
4-NITROSODIPHENYLAMINE
N-PHENYL-P-PHENYLENEDIAMINE
P-PHENYLENEDIAMINE
PSEUDO-MAUVEINE

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10.3184/174751914X14033559668812

JCR A water soluble phenazine dye
This is the author's accepted manuscript of a journal published in the Journal of Chemical Research
Accepted author manuscript, 310 KB

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title = "1-(Phenylamino)pseudo-mauveine: a new water soluble phenazine dye ",

abstract = "1-(Phenylamino)pseudo-mauveine was prepared by the oxidation of 1,3,5-tris(phenylamino)benzene and p-phenylenediamine with potassium dichromate. The absorption maximum of 535 nm is shifted hypsochromically by about 20 nm compared to that for pseudo-mauveine. Condensation of 1,3,5-tris(phenylamino)benzene with 4-nitrosodiphenylamine under strongly acidic conditions gave 1,3,7-tris(phenylamino)-5-phenylphenazinium sulfate and 10-phenyl-6,8-bis(phenylamino)-2,10-dihydrophenazin-2-one. ",

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author = "Plater, \{M. John\} and Toby Jackson",

year = "2014",

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day = "1",

doi = "10.3184/174751914X14033559668812",

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journal = "Journal of Chemical Research",

issn = "0308-2342",

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TY - JOUR

T1 - 1-(Phenylamino)pseudo-mauveine

T2 - a new water soluble phenazine dye

AU - Plater, M. John

AU - Jackson, Toby

PY - 2014/7/1

Y1 - 2014/7/1

N2 - 1-(Phenylamino)pseudo-mauveine was prepared by the oxidation of 1,3,5-tris(phenylamino)benzene and p-phenylenediamine with potassium dichromate. The absorption maximum of 535 nm is shifted hypsochromically by about 20 nm compared to that for pseudo-mauveine. Condensation of 1,3,5-tris(phenylamino)benzene with 4-nitrosodiphenylamine under strongly acidic conditions gave 1,3,7-tris(phenylamino)-5-phenylphenazinium sulfate and 10-phenyl-6,8-bis(phenylamino)-2,10-dihydrophenazin-2-one.

AB - 1-(Phenylamino)pseudo-mauveine was prepared by the oxidation of 1,3,5-tris(phenylamino)benzene and p-phenylenediamine with potassium dichromate. The absorption maximum of 535 nm is shifted hypsochromically by about 20 nm compared to that for pseudo-mauveine. Condensation of 1,3,5-tris(phenylamino)benzene with 4-nitrosodiphenylamine under strongly acidic conditions gave 1,3,7-tris(phenylamino)-5-phenylphenazinium sulfate and 10-phenyl-6,8-bis(phenylamino)-2,10-dihydrophenazin-2-one.

KW - 1,3,5-TRIS(PHENYLAMINO)BENZENE

KW - 4-NITROSODIPHENYLAMINE

KW - N-PHENYL-P-PHENYLENEDIAMINE

KW - P-PHENYLENEDIAMINE

KW - PSEUDO-MAUVEINE

U2 - 10.3184/174751914X14033559668812

DO - 10.3184/174751914X14033559668812

M3 - Article

SN - 0308-2342

VL - 38

SP - 437

EP - 442

JO - Journal of Chemical Research

JF - Journal of Chemical Research

IS - 7

ER -

1-(Phenylamino)pseudo-mauveine: a new water soluble phenazine dye

Abstract

Keywords

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