1,5-diaminopentane as a structure-directing agent for zincophosphate networks: Zn3(PO4)2(C5H14N2)2·3H2O and C5H16N2·Zn3(PO4)2(HPO4)·H2O

William T A Harrison; William R. Currie

doi:10.3390/cryst2030974

1,5-diaminopentane as a structure-directing agent for zincophosphate networks: Zn3(PO4)2(C5H14N2)2·3H2O and C5H16N2·Zn3(PO4)2(HPO4)·H2O

William T A Harrison
, William R. Currie

Chemistry

University of Aberdeen

Research output: Contribution to journal › Article › peer-review

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Abstract

The crystal structures of two zincophosphate networks prepared in the presence of 1,5-diaminopentane (dap) are described. In Zn₃(PO₄)₂(C₅H₁₄N₂)₂•3H₂O (1) the dap forms Zn-N coordinate bonds to generate an unusual three-dimensional "hybrid" framework constructed from ZnO₃N, ZnO₂N₂ and PO₄ tetrahedra with three different types of elongated channels occupied by water molecules. In C₅H₁₆N₂•Zn₃(PO₄)₂(HPO₄)•H₂O; (2) the doubly-protonated H₂dap acts in a more typical way to template double layers of vertex-sharing ZnO₄, PO₄ and HPO₄ tetrahedra incorporating 10-rings and interacts with the inorganic component via N-H O hydrogen bonds. Crystal data: 1 (C₁₀H₃₄N₄O₁₁P₂Zn₃), M_r = 644.46, monoclinic, C2 (No. 4), Z = 4, a = 25.302 (7) Å, b = 4.9327 (13) Å, c = 19.808 (6) Å, b = 107.377 (8)°, V = 2359.4 (12) Å³, R(F) = 0.054, wR(F²) = 0.139. 2 (C₅H₁₉N₂O₁₃P₃Zn₃), M_r = 604.24, monoclinic, P2₁/c (No. 14), Z = 4, a= 11.3275 (15) Å, b = 8.3235 (11) Å, c = 18.588 (2) Å, b = 96.979 (3)°, V = 1739.6 (4) Å³, R(F) = 0.056, wR(F²) = 0.119.

Original language	English
Pages (from-to)	974-983
Number of pages	10
Journal	Liquid Crystals
Volume	2
Issue number	3
DOIs	https://doi.org/10.3390/cryst2030974
Publication status	Published - 16 Jul 2012

Keywords

Framework
Hydrogen bonds
Template
Zincophosphate

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10.3390/cryst2030974Licence: CC BY

1,5-Diaminopentane As A Structure-Directing Agent for Zincophosphate Networks: Zn3(PO4)2(C5H14N2)2·3H2O and C5H16N2·Zn3(PO4)2(HPO4)·H2O
© 2012 by the authors; licensee MDPI, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
Final published version, 876 KBLicence: CC BY

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@article{08bade4179364ac8b5607a279738457a,

title = "1,5-diaminopentane as a structure-directing agent for zincophosphate networks: Zn3(PO4)2(C5H14N2)2·3H2O and C5H16N2·Zn3(PO4)2(HPO4)·H2O",

abstract = "The crystal structures of two zincophosphate networks prepared in the presence of 1,5-diaminopentane (dap) are described. In Zn3(PO4)2(C5H14N2)2•3H2O (1) the dap forms Zn-N coordinate bonds to generate an unusual three-dimensional {"}hybrid{"} framework constructed from ZnO3N, ZnO2N2 and PO4 tetrahedra with three different types of elongated channels occupied by water molecules. In C5H16N2•Zn3(PO4)2(HPO4)•H2O; (2) the doubly-protonated H2dap acts in a more typical way to template double layers of vertex-sharing ZnO4, PO4 and HPO4 tetrahedra incorporating 10-rings and interacts with the inorganic component via N-H O hydrogen bonds. Crystal data: 1 (C10H34N4O11P2Zn3), Mr = 644.46, monoclinic, C2 (No. 4), Z = 4, a = 25.302 (7) {\AA}, b = 4.9327 (13) {\AA}, c = 19.808 (6) {\AA}, b = 107.377 (8)°, V = 2359.4 (12) {\AA}3, R(F) = 0.054, wR(F2) = 0.139. 2 (C5H19N2O13P3Zn3), Mr = 604.24, monoclinic, P21/c (No. 14), Z = 4, a= 11.3275 (15) {\AA}, b = 8.3235 (11) {\AA}, c = 18.588 (2) {\AA}, b = 96.979 (3)°, V = 1739.6 (4) {\AA}3, R(F) = 0.056, wR(F2) = 0.119.",

keywords = "Framework, Hydrogen bonds, Template, Zincophosphate",

author = "Harrison, \{William T A\} and Currie, \{William R.\}",

year = "2012",

month = jul,

day = "16",

doi = "10.3390/cryst2030974",

language = "English",

volume = "2",

pages = "974--983",

journal = "Liquid Crystals",

issn = "0267-8292",

publisher = "Taylor and Francis Ltd.",

number = "3",

}

TY - JOUR

T1 - 1,5-diaminopentane as a structure-directing agent for zincophosphate networks

T2 - Zn3(PO4)2(C5H14N2)2·3H2O and C5H16N2·Zn3(PO4)2(HPO4)·H2O

AU - Harrison, William T A

AU - Currie, William R.

PY - 2012/7/16

Y1 - 2012/7/16

N2 - The crystal structures of two zincophosphate networks prepared in the presence of 1,5-diaminopentane (dap) are described. In Zn3(PO4)2(C5H14N2)2•3H2O (1) the dap forms Zn-N coordinate bonds to generate an unusual three-dimensional "hybrid" framework constructed from ZnO3N, ZnO2N2 and PO4 tetrahedra with three different types of elongated channels occupied by water molecules. In C5H16N2•Zn3(PO4)2(HPO4)•H2O; (2) the doubly-protonated H2dap acts in a more typical way to template double layers of vertex-sharing ZnO4, PO4 and HPO4 tetrahedra incorporating 10-rings and interacts with the inorganic component via N-H O hydrogen bonds. Crystal data: 1 (C10H34N4O11P2Zn3), Mr = 644.46, monoclinic, C2 (No. 4), Z = 4, a = 25.302 (7) Å, b = 4.9327 (13) Å, c = 19.808 (6) Å, b = 107.377 (8)°, V = 2359.4 (12) Å3, R(F) = 0.054, wR(F2) = 0.139. 2 (C5H19N2O13P3Zn3), Mr = 604.24, monoclinic, P21/c (No. 14), Z = 4, a= 11.3275 (15) Å, b = 8.3235 (11) Å, c = 18.588 (2) Å, b = 96.979 (3)°, V = 1739.6 (4) Å3, R(F) = 0.056, wR(F2) = 0.119.

AB - The crystal structures of two zincophosphate networks prepared in the presence of 1,5-diaminopentane (dap) are described. In Zn3(PO4)2(C5H14N2)2•3H2O (1) the dap forms Zn-N coordinate bonds to generate an unusual three-dimensional "hybrid" framework constructed from ZnO3N, ZnO2N2 and PO4 tetrahedra with three different types of elongated channels occupied by water molecules. In C5H16N2•Zn3(PO4)2(HPO4)•H2O; (2) the doubly-protonated H2dap acts in a more typical way to template double layers of vertex-sharing ZnO4, PO4 and HPO4 tetrahedra incorporating 10-rings and interacts with the inorganic component via N-H O hydrogen bonds. Crystal data: 1 (C10H34N4O11P2Zn3), Mr = 644.46, monoclinic, C2 (No. 4), Z = 4, a = 25.302 (7) Å, b = 4.9327 (13) Å, c = 19.808 (6) Å, b = 107.377 (8)°, V = 2359.4 (12) Å3, R(F) = 0.054, wR(F2) = 0.139. 2 (C5H19N2O13P3Zn3), Mr = 604.24, monoclinic, P21/c (No. 14), Z = 4, a= 11.3275 (15) Å, b = 8.3235 (11) Å, c = 18.588 (2) Å, b = 96.979 (3)°, V = 1739.6 (4) Å3, R(F) = 0.056, wR(F2) = 0.119.

KW - Framework

KW - Hydrogen bonds

KW - Template

KW - Zincophosphate

UR - https://www.scopus.com/pages/publications/84901340399

U2 - 10.3390/cryst2030974

DO - 10.3390/cryst2030974

M3 - Article

AN - SCOPUS:84901340399

SN - 0267-8292

VL - 2

SP - 974

EP - 983

JO - Liquid Crystals

JF - Liquid Crystals

IS - 3

ER -

1,5-diaminopentane as a structure-directing agent for zincophosphate networks: Zn3(PO4)2(C5H14N2)2·3H2O and C5H16N2·Zn3(PO4)2(HPO4)·H2O

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