2,6-Diiodo-4-nitrophenol, 2,6-diiodo-4-nitrophenyl acetate and 2,6-diiodo-4-nitroanisole: interplay of hydrogen bonds, iodo-nitro interactions and aromatic [pi]-[pi]-stacking interactions to give supramolecular structures in one, two and three dimensions

S J  Garden; F R  da Cunha; J L  Wardell; J M S  Skakle; J N  Low; C  Glidewell

doi:10.1107/S0108270102010776

2,6-Diiodo-4-nitrophenol, 2,6-diiodo-4-nitrophenyl acetate and 2,6-diiodo-4-nitroanisole: interplay of hydrogen bonds, iodo-nitro interactions and aromatic [pi]-[pi]-stacking interactions to give supramolecular structures in one, two and three dimensions

S J Garden
, F R da Cunha
, J L Wardell
, J M S Skakle
, J N Low
, C Glidewell

Physics

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

13 Downloads (Pure)

Abstract

In 2,6-diiodo-4-nitrophenol, C6H3I2NO3, the molecules are linked, by an O-H...O hydrogen bond and two iodo-nitro interactions, into sheets, which are further linked into a three-dimensional framework by aromatic pi-pi-stacking interactions. The molecules of 2,6-diiodo-4-nitrophenyl acetate, C8H5I2NO4, lie across a mirror plane in space group Pnma, with the acetyl group on the mirror, and they are linked by a single iodo-nitro interaction to form isolated sheets. The molecules of 2,6-diiodo-4-nitroanisole, C7H5I2NO3, are linked into isolated chains by a single two-centre iodo-nitro interaction.

Original language	English
Pages (from-to)	o463-o466
Number of pages	4
Journal	Acta Crystallographica Section C, Crystal Structure Communications
Volume	58
Issue number	8
DOIs	https://doi.org/10.1107/S0108270102010776
Publication status	Published - Aug 2002

Keywords

crystals

Access to Document

10.1107/S0108270102010776

Acta Cryst C58 o463 (2002)
Garden, SJ, da Cunha, FR, Wardell, JL, Skakle, JMS, Low, JN & Glidewell, C 2002, '2,6-Diiodo-4-nitrophenol, 2,6-diiodo-4-nitrophenyl acetate and 2,6-diiodo-4-nitroanisole: interplay of hydrogen bonds, iodo-nitro interactions and aromatic [pi]-[pi]-stacking interactions to give supramolecular structures in one, two and three dimensions' Acta Crystallographica Section C, Crystal Structure Communications, vol 58, no. 8, pp. o463-o466. DOI: 10.1107/S0108270102010776
Final published version, 484 KB

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Garden, S. J., da Cunha, F. R., Wardell, J. L., Skakle, J. M. S., Low, J. N., & Glidewell, C. (2002). 2,6-Diiodo-4-nitrophenol, 2,6-diiodo-4-nitrophenyl acetate and 2,6-diiodo-4-nitroanisole: interplay of hydrogen bonds, iodo-nitro interactions and aromatic [pi]-[pi]-stacking interactions to give supramolecular structures in one, two and three dimensions. Acta Crystallographica Section C, Crystal Structure Communications, 58(8), o463-o466. https://doi.org/10.1107/S0108270102010776

2,6-Diiodo-4-nitrophenol, 2,6-diiodo-4-nitrophenyl acetate and 2,6-diiodo-4-nitroanisole: interplay of hydrogen bonds, iodo-nitro interactions and aromatic [pi]-[pi]-stacking interactions to give supramolecular structures in one, two and three dimensions. / Garden, S J ; da Cunha, F R ; Wardell, J L et al.
In: Acta Crystallographica Section C, Crystal Structure Communications, Vol. 58, No. 8, 08.2002, p. o463-o466.

Research output: Contribution to journal › Article › peer-review

Garden, SJ, da Cunha, FR, Wardell, JL, Skakle, JMS, Low, JN & Glidewell, C 2002, '2,6-Diiodo-4-nitrophenol, 2,6-diiodo-4-nitrophenyl acetate and 2,6-diiodo-4-nitroanisole: interplay of hydrogen bonds, iodo-nitro interactions and aromatic [pi]-[pi]-stacking interactions to give supramolecular structures in one, two and three dimensions', Acta Crystallographica Section C, Crystal Structure Communications, vol. 58, no. 8, pp. o463-o466. https://doi.org/10.1107/S0108270102010776

Garden SJ, da Cunha FR, Wardell JL, Skakle JMS, Low JN, Glidewell C. 2,6-Diiodo-4-nitrophenol, 2,6-diiodo-4-nitrophenyl acetate and 2,6-diiodo-4-nitroanisole: interplay of hydrogen bonds, iodo-nitro interactions and aromatic [pi]-[pi]-stacking interactions to give supramolecular structures in one, two and three dimensions. Acta Crystallographica Section C, Crystal Structure Communications. 2002 Aug;58(8):o463-o466. doi: 10.1107/S0108270102010776

Garden, S J ; da Cunha, F R ; Wardell, J L et al. / 2,6-Diiodo-4-nitrophenol, 2,6-diiodo-4-nitrophenyl acetate and 2,6-diiodo-4-nitroanisole: interplay of hydrogen bonds, iodo-nitro interactions and aromatic [pi]-[pi]-stacking interactions to give supramolecular structures in one, two and three dimensions. In: Acta Crystallographica Section C, Crystal Structure Communications. 2002 ; Vol. 58, No. 8. pp. o463-o466.

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