(4-Nitrophenylsulfanylmethyl)triphenylstannane and (4-nitrophenylsulfonylmethyl)triphenylstannane: R22(X) rings (X is 10, 18 or 24) and C-H...p interactions

Jan Skakle; J. L. Wardell; S. M. S. V. Wardell

doi:10.1107/S0108270102010375

(4-Nitrophenylsulfanylmethyl)triphenylstannane and (4-nitrophenylsulfonylmethyl)triphenylstannane: R₂²(X) rings (X is 10, 18 or 24) and C-H...p interactions

Jan Skakle
, J. L. Wardell
, S. M. S. V. Wardell

Physics

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

17 Downloads (Pure)

Abstract

In the crystal structures of (4-nitrophenylsulfanylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO2S)], (I), and (4-nitrophenylsulfonylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO4S)], (II), the molecules are linked by paired C-H...O hydrogen bonds into centrosymmetric dimers which combine to form sheets. In (I), two such dimers form to give R-2(2) (10) and R-2(2) (24) rings. In (II), similar dimers form, here with R-2(2) (10) and R-2(2) (18) rings, but with an additional dimer due to the presence of the sulfone group, giving R-2(2) (10) rings. In both structures, C-H...pi interactions lead to a doubling of the width of the sheets.

Formula: [Sn(C_{6H₅)₃(C₇H₆NO₂S)] and [Sn(C₆H₅)₃(C₇H₆NO₄S)]}

Original language	English
Pages (from-to)	m413-m417
Number of pages	5
Journal	Acta Crystallographica Section C, Crystal Structure Communications
Volume	58
Issue number	7
DOIs	https://doi.org/10.1107/S0108270102010375
Publication status	Published - Jul 2002

Keywords

O Hydrogen-bonds
substituted organotin compounds
molecular-structure
disulfide
crystal

Access to Document

10.1107/S0108270102010375

Acta Cryst C58 m413 (2002)
Skakle, J, Wardell, JL & Wardell, SMSV 2002, '(4-Nitrophenylsulfanylmethyl)triphenylstannane and (4-nitrophenylsulfonylmethyl)triphenylstannane: R22(X) rings (X is 10, 18 or 24) and C-H...p interactions' Acta Crystallographica Section C, Crystal Structure Communications, vol 58, no. 7, pp. m413-m417. DOI: 10.1107/S0108270102010375
Final published version, 300 KB

Cite this

(4-Nitrophenylsulfanylmethyl)triphenylstannane and (4-nitrophenylsulfonylmethyl)triphenylstannane: R₂²(X) rings (X is 10, 18 or 24) and C-H...p interactions. / Skakle, Jan; Wardell, J. L.; Wardell, S. M. S. V.
In: Acta Crystallographica Section C, Crystal Structure Communications, Vol. 58, No. 7, 07.2002, p. m413-m417.

Research output: Contribution to journal › Article › peer-review

@article{2006194f55184a1489aa0522b804d28e,

title = "(4-Nitrophenylsulfanylmethyl)triphenylstannane and (4-nitrophenylsulfonylmethyl)triphenylstannane: R22(X) rings (X is 10, 18 or 24) and C-H...p interactions",

abstract = "In the crystal structures of (4-nitrophenylsulfanylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO2S)], (I), and (4-nitrophenylsulfonylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO4S)], (II), the molecules are linked by paired C-H...O hydrogen bonds into centrosymmetric dimers which combine to form sheets. In (I), two such dimers form to give R-2(2) (10) and R-2(2) (24) rings. In (II), similar dimers form, here with R-2(2) (10) and R-2(2) (18) rings, but with an additional dimer due to the presence of the sulfone group, giving R-2(2) (10) rings. In both structures, C-H...pi interactions lead to a doubling of the width of the sheets. Formula: [Sn(C6H5)3(C7H6NO2S)] and [Sn(C6H5)3(C7H6NO4S)]",

keywords = "O Hydrogen-bonds, substituted organotin compounds, molecular-structure, disulfide, crystal",

author = "Jan Skakle and Wardell, \{J. L.\} and Wardell, \{S. M. S. V.\}",

year = "2002",

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T1 - (4-Nitrophenylsulfanylmethyl)triphenylstannane and (4-nitrophenylsulfonylmethyl)triphenylstannane: R22(X) rings (X is 10, 18 or 24) and C-H...p interactions

AU - Skakle, Jan

AU - Wardell, J. L.

AU - Wardell, S. M. S. V.

PY - 2002/7

Y1 - 2002/7

N2 - In the crystal structures of (4-nitrophenylsulfanylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO2S)], (I), and (4-nitrophenylsulfonylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO4S)], (II), the molecules are linked by paired C-H...O hydrogen bonds into centrosymmetric dimers which combine to form sheets. In (I), two such dimers form to give R-2(2) (10) and R-2(2) (24) rings. In (II), similar dimers form, here with R-2(2) (10) and R-2(2) (18) rings, but with an additional dimer due to the presence of the sulfone group, giving R-2(2) (10) rings. In both structures, C-H...pi interactions lead to a doubling of the width of the sheets. Formula: [Sn(C6H5)3(C7H6NO2S)] and [Sn(C6H5)3(C7H6NO4S)]

AB - In the crystal structures of (4-nitrophenylsulfanylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO2S)], (I), and (4-nitrophenylsulfonylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO4S)], (II), the molecules are linked by paired C-H...O hydrogen bonds into centrosymmetric dimers which combine to form sheets. In (I), two such dimers form to give R-2(2) (10) and R-2(2) (24) rings. In (II), similar dimers form, here with R-2(2) (10) and R-2(2) (18) rings, but with an additional dimer due to the presence of the sulfone group, giving R-2(2) (10) rings. In both structures, C-H...pi interactions lead to a doubling of the width of the sheets. Formula: [Sn(C6H5)3(C7H6NO2S)] and [Sn(C6H5)3(C7H6NO4S)]

KW - O Hydrogen-bonds

KW - substituted organotin compounds

KW - molecular-structure

KW - disulfide

KW - crystal

U2 - 10.1107/S0108270102010375

DO - 10.1107/S0108270102010375

M3 - Article

SN - 0108-2701

VL - 58

SP - m413-m417

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

IS - 7

ER -