Barium cobalt chloride selenite, Ba2CoCl2(SeO3)(2)

Magnus G. Johnston; William T. A.  Harrison

doi:10.1107/S1600536802009005

Barium cobalt chloride selenite, Ba2CoCl2(SeO3)(2)

Magnus G. Johnston
, William T. A. Harrison

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15 Citations (Web of Science)

Abstract

Hydrothermally synthesized Ba2CoCl2(SeO3)2 contains [001] chains of corner-linked CoO4Cl2 [dav(Co-O) = 2.073 (3) Å and d(Co-Cl) = 2.544 (2) Å] octahedra and SeO3 groups [dav(Se-O) = 1.702 (3) Å]. These chains stack in the [100] direction, with 10-coordinate Ba2+ cations (to seven O and three Cl) binding the chains in the [010] direction. Most of the atoms occupy special positions: Co has site symmetry 2/m and Ba, Se, Cl and one O atom have site symmetry m.

Original language	English
Pages (from-to)	i49-i51
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	E58
DOIs	https://doi.org/10.1107/S1600536802009005
Publication status	Published - 2002

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title = "Barium cobalt chloride selenite, Ba2CoCl2(SeO3)(2)",

abstract = "Hydrothermally synthesized Ba2CoCl2(SeO3)2 contains [001] chains of corner-linked CoO4Cl2 [dav(Co-O) = 2.073 (3) {\AA} and d(Co-Cl) = 2.544 (2) {\AA}] octahedra and SeO3 groups [dav(Se-O) = 1.702 (3) {\AA}]. These chains stack in the [100] direction, with 10-coordinate Ba2+ cations (to seven O and three Cl) binding the chains in the [010] direction. Most of the atoms occupy special positions: Co has site symmetry 2/m and Ba, Se, Cl and one O atom have site symmetry m.",

author = "Johnston, \{Magnus G.\} and Harrison, \{William T. A.\}",

year = "2002",

doi = "10.1107/S1600536802009005",

language = "English",

volume = "E58",

pages = "i49--i51",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Barium cobalt chloride selenite, Ba2CoCl2(SeO3)(2)

AU - Johnston, Magnus G.

AU - Harrison, William T. A.

PY - 2002

Y1 - 2002

N2 - Hydrothermally synthesized Ba2CoCl2(SeO3)2 contains [001] chains of corner-linked CoO4Cl2 [dav(Co-O) = 2.073 (3) Å and d(Co-Cl) = 2.544 (2) Å] octahedra and SeO3 groups [dav(Se-O) = 1.702 (3) Å]. These chains stack in the [100] direction, with 10-coordinate Ba2+ cations (to seven O and three Cl) binding the chains in the [010] direction. Most of the atoms occupy special positions: Co has site symmetry 2/m and Ba, Se, Cl and one O atom have site symmetry m.

AB - Hydrothermally synthesized Ba2CoCl2(SeO3)2 contains [001] chains of corner-linked CoO4Cl2 [dav(Co-O) = 2.073 (3) Å and d(Co-Cl) = 2.544 (2) Å] octahedra and SeO3 groups [dav(Se-O) = 1.702 (3) Å]. These chains stack in the [100] direction, with 10-coordinate Ba2+ cations (to seven O and three Cl) binding the chains in the [010] direction. Most of the atoms occupy special positions: Co has site symmetry 2/m and Ba, Se, Cl and one O atom have site symmetry m.

U2 - 10.1107/S1600536802009005

DO - 10.1107/S1600536802009005

M3 - Article

SN - 1600-5368

VL - E58

SP - i49-i51

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

ER -

Barium cobalt chloride selenite, Ba2CoCl2(SeO3)(2)

Abstract

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