Bis(acetonitrile-kappa N)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazatetradecane-kappa N-4]copper(II) bis{tetrakis[3,5-bis-(trifluoromethyl)phenyl]borate} 0.31-hydrate

J M S  Skakle; M V D R E  Silva; J L  Wardell; S M S V  Wardell

doi:10.1107/S0108270103016743

Bis(acetonitrile-kappa N)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazatetradecane-kappa N-4]copper(II) bis{tetrakis[3,5-bis-(trifluoromethyl)phenyl]borate} 0.31-hydrate

J M S Skakle, M V D R E Silva, J L Wardell, S M S V Wardell

Physics

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [Cu(C2H3N)(2)(C10H24N4)](C32H12BF24)(2).0.31H(2)O, crystallizes as an ionic species with no interactions between the ions. The [Cu-II(cyclam)(MeCN)(2)](2+) dication (cyclam is 1,4,8,11-tetraazatetradecane), located on a 2/m symmetry site, forms as a distorted octahedral species with four Cu-N-cyclam bonds of 2.013 (2) Angstrom and two C-N-MeCN bonds of 2.499 (4) Angstrom. The [B{C6H3(CF3)- 3,5}(4)](-) anion, located on a twofold axis, is a distorted octahedral species. A small amount of water is present, occupying sites between columns of ions.

Original language	English
Pages (from-to)	m413-m415
Number of pages	3
Journal	Acta Crystallographica Section C, Crystal Structure Communications
Volume	C59
Issue number	10
DOIs	https://doi.org/10.1107/S0108270103016743
Publication status	Published - 2003

Keywords

molecular-structure
crystal-structure
copper(II)
complexes

Access to Document

10.1107/S0108270103016743

Cite this

Skakle, J. M. S., Silva, M. V. D. R. E., Wardell, J. L., & Wardell, S. M. S. V. (2003). Bis(acetonitrile-kappa N)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazatetradecane-kappa N-4]copper(II) bis{tetrakis[3,5-bis-(trifluoromethyl)phenyl]borate} 0.31-hydrate. Acta Crystallographica Section C, Crystal Structure Communications, C59(10), m413-m415. https://doi.org/10.1107/S0108270103016743

Bis(acetonitrile-kappa N)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazatetradecane-kappa N-4]copper(II) bis{tetrakis[3,5-bis-(trifluoromethyl)phenyl]borate} 0.31-hydrate. / Skakle, J M S ; Silva, M V D R E ; Wardell, J L et al.
In: Acta Crystallographica Section C, Crystal Structure Communications, Vol. C59, No. 10, 2003, p. m413-m415.

Research output: Contribution to journal › Article › peer-review

@article{d336133d191a49119787491d4d54cd68,

title = "Bis(acetonitrile-kappa N)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazatetradecane-kappa N-4]copper(II) bis{tetrakis[3,5-bis-(trifluoromethyl)phenyl]borate} 0.31-hydrate",

abstract = "The title compound, [Cu(C2H3N)(2)(C10H24N4)](C32H12BF24)(2).0.31H(2)O, crystallizes as an ionic species with no interactions between the ions. The [Cu-II(cyclam)(MeCN)(2)](2+) dication (cyclam is 1,4,8,11-tetraazatetradecane), located on a 2/m symmetry site, forms as a distorted octahedral species with four Cu-N-cyclam bonds of 2.013 (2) Angstrom and two C-N-MeCN bonds of 2.499 (4) Angstrom. The [B{C6H3(CF3)- 3,5}(4)](-) anion, located on a twofold axis, is a distorted octahedral species. A small amount of water is present, occupying sites between columns of ions.",

keywords = "molecular-structure, crystal-structure, copper(II), complexes",

author = "Skakle, {J M S} and Silva, {M V D R E} and Wardell, {J L} and Wardell, {S M S V}",

year = "2003",

doi = "10.1107/S0108270103016743",

language = "English",

volume = "C59",

pages = "m413--m415",

journal = "Acta Crystallographica Section C, Crystal Structure Communications",

issn = "0108-2701",

publisher = "Wiley-Blackwell ",

number = "10",

}

TY - JOUR

T1 - Bis(acetonitrile-kappa N)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazatetradecane-kappa N-4]copper(II) bis{tetrakis[3,5-bis-(trifluoromethyl)phenyl]borate} 0.31-hydrate

AU - Skakle, J M S

AU - Silva, M V D R E

AU - Wardell, J L

AU - Wardell, S M S V

PY - 2003

Y1 - 2003

N2 - The title compound, [Cu(C2H3N)(2)(C10H24N4)](C32H12BF24)(2).0.31H(2)O, crystallizes as an ionic species with no interactions between the ions. The [Cu-II(cyclam)(MeCN)(2)](2+) dication (cyclam is 1,4,8,11-tetraazatetradecane), located on a 2/m symmetry site, forms as a distorted octahedral species with four Cu-N-cyclam bonds of 2.013 (2) Angstrom and two C-N-MeCN bonds of 2.499 (4) Angstrom. The [B{C6H3(CF3)- 3,5}(4)](-) anion, located on a twofold axis, is a distorted octahedral species. A small amount of water is present, occupying sites between columns of ions.

AB - The title compound, [Cu(C2H3N)(2)(C10H24N4)](C32H12BF24)(2).0.31H(2)O, crystallizes as an ionic species with no interactions between the ions. The [Cu-II(cyclam)(MeCN)(2)](2+) dication (cyclam is 1,4,8,11-tetraazatetradecane), located on a 2/m symmetry site, forms as a distorted octahedral species with four Cu-N-cyclam bonds of 2.013 (2) Angstrom and two C-N-MeCN bonds of 2.499 (4) Angstrom. The [B{C6H3(CF3)- 3,5}(4)](-) anion, located on a twofold axis, is a distorted octahedral species. A small amount of water is present, occupying sites between columns of ions.

KW - molecular-structure

KW - crystal-structure

KW - copper(II)

KW - complexes

U2 - 10.1107/S0108270103016743

DO - 10.1107/S0108270103016743

M3 - Article

SN - 0108-2701

VL - C59

SP - m413-m415

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

IS - 10

ER -

Bis(acetonitrile-kappa N)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazatetradecane-kappa N-4]copper(II) bis{tetrakis[3,5-bis-(trifluoromethyl)phenyl]borate} 0.31-hydrate

Abstract

Keywords

Access to Document

Fingerprint

Cite this