Different weak interactions in the crystals of three isomeric (E)-N-methyl-N0-(nitrobenzylidene)- 2-(thiophen-2-yl)acetohydrazides

Laura N F Cardoso; Thais C M Noguiera; Carlos R Kaiser; James L Wardell; Marcus V N de Souza; Shaun T Lancaster; William T A Harrison

doi:10.1107/S2056989016016856

Different weak interactions in the crystals of three isomeric (E)-N-methyl-N0-(nitrobenzylidene)- 2-(thiophen-2-yl)acetohydrazides

Laura N F Cardoso
, Thais C M Noguiera
, Carlos R Kaiser
, James L Wardell
, Marcus V N de Souza
, Shaun T Lancaster
, William T A Harrison

Chemistry

Universidade Federal do Rio de Janeiro
Instituto de Tecnologia em Fármacos, FarManguinhos

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

16 Downloads (Pure)

Abstract

The crystal structures of three isomeric (E)-N-methyl-N′-(nitrobenzylidene)-2-(thiophen-2-yl)acetohydrazides (formula C14H13N3O3S) are described, with the nitro group in ortho, meta and para positions in the benzene ring. In each crystal structure, molecules are linked by various weak interactions (C—H⋯O and C—H⋯π bonds, and π–π stacking), leading to three-dimensional networks in each case, but with little similarity between them.

Original language	English
Pages (from-to)	1677-1682
Number of pages	6
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	72
Issue number	12
Early online date	1 Nov 2016
DOIs	https://doi.org/10.1107/S2056989016016856
Publication status	Published - 1 Dec 2016

Bibliographical note

We thank the EPSRC National Crystallography Service (University of Southampton) for X-ray data collection.

Keywords

crystal structure
carbohydrazide
methylation
weak hydrogen bonds

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10.1107/S2056989016016856Licence: CC BY

Different weak interactions in the crystals of three isomeric (E)-N-methyl-N0-(nitrobenzylidene)- 2-(thiophen-2-yl)acetohydrazides
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Cite this

Cardoso, L. N. F., Noguiera, T. C. M., Kaiser, C. R., Wardell, J. L., de Souza, M. V. N., Lancaster, S. T., & Harrison, W. T. A. (2016). Different weak interactions in the crystals of three isomeric (E)-N-methyl-N0-(nitrobenzylidene)- 2-(thiophen-2-yl)acetohydrazides. Acta Crystallographica Section E: Crystallographic Communications, 72(12), 1677-1682. https://doi.org/10.1107/S2056989016016856

Different weak interactions in the crystals of three isomeric (E)-N-methyl-N0-(nitrobenzylidene)- 2-(thiophen-2-yl)acetohydrazides. / Cardoso, Laura N F; Noguiera, Thais C M; Kaiser, Carlos R et al.
In: Acta Crystallographica Section E: Crystallographic Communications, Vol. 72, No. 12, 01.12.2016, p. 1677-1682.

Research output: Contribution to journal › Article › peer-review

Cardoso, LNF, Noguiera, TCM, Kaiser, CR, Wardell, JL, de Souza, MVN, Lancaster, ST & Harrison, WTA 2016, 'Different weak interactions in the crystals of three isomeric (E)-N-methyl-N0-(nitrobenzylidene)- 2-(thiophen-2-yl)acetohydrazides', Acta Crystallographica Section E: Crystallographic Communications, vol. 72, no. 12, pp. 1677-1682. https://doi.org/10.1107/S2056989016016856

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abstract = "The crystal structures of three isomeric (E)-N-methyl-N′-(nitrobenzylidene)-2-(thiophen-2-yl)acetohydrazides (formula C14H13N3O3S) are described, with the nitro group in ortho, meta and para positions in the benzene ring. In each crystal structure, molecules are linked by various weak interactions (C{\textemdash}H⋯O and C{\textemdash}H⋯π bonds, and π{\textendash}π stacking), leading to three-dimensional networks in each case, but with little similarity between them.",

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AU - de Souza, Marcus V N

AU - Lancaster, Shaun T

AU - Harrison, William T A

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Different weak interactions in the crystals of three isomeric (E)-N-methyl-N0-(nitrobenzylidene)- 2-(thiophen-2-yl)acetohydrazides

Abstract

Bibliographical note

Keywords

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