TY - JOUR
T1 - Diphenyl(2-thioxo-1,3-dithiole-4,5-di-thiolato-S,S ')plumbane at 295 K and diphenyl(2-thioxo-1,3-dithiole-4,5-di-thiolato-S,S ')stannane at 150 K
AU - Skakle, J M S
AU - Wardell, J L
AU - Wardell, S M S V
PY - 2001
Y1 - 2001
N2 - Molecules of diphenyl(2-thioxo-1,3-dithiole-4,5-dithiolato-S,S')plumbane, [Pb(C3S5)(C6H5)(2)], are linked into sheets via two intermolecular Pb . . .S-thione interactions of 3.322 (4) and 3.827 (4) Angstrom; the Pb centre has a distorted octahedral geometry. In contrast, molecules of diphenyl(2-thioxo-1,3-dithiole-4,5-ithiolato-S,S')stannane, [Sn(C3S5)(C6H5)(2)], are linked into chains via a single intermolecular SnDSthione interaction of 2.8174 (9) Angstrom; the Sn centre has a distorted trigonal-bipyramidal geometry.
AB - Molecules of diphenyl(2-thioxo-1,3-dithiole-4,5-dithiolato-S,S')plumbane, [Pb(C3S5)(C6H5)(2)], are linked into sheets via two intermolecular Pb . . .S-thione interactions of 3.322 (4) and 3.827 (4) Angstrom; the Pb centre has a distorted octahedral geometry. In contrast, molecules of diphenyl(2-thioxo-1,3-dithiole-4,5-ithiolato-S,S')stannane, [Sn(C3S5)(C6H5)(2)], are linked into chains via a single intermolecular SnDSthione interaction of 2.8174 (9) Angstrom; the Sn centre has a distorted trigonal-bipyramidal geometry.
KW - CRYSTAL
M3 - Article
SN - 0108-2701
VL - 57
SP - 787
EP - 789
JO - Acta Crystallographica Section C, Crystal Structure Communications
JF - Acta Crystallographica Section C, Crystal Structure Communications
ER -