Methylation of Toluene with Methane over ZSM-5 Catalysts

A. Adebajo; Russell Francis Howe; C. Long

doi:10.1021/ef0002086

Methylation of Toluene with Methane over ZSM-5 Catalysts

A. Adebajo, Russell Francis Howe, C. Long

Chemistry

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The methylation of toluene with methane in the presence of oxygen over zeolite catalysts is shown to be complicated by extensive disproportionation, hydrodealkylation, and hydrocracking reactions. However, it appears that these undesired reactions can be minimized, to enhance the methylation reaction, by using zeolites with reduced Bronsted acidity.

Original language	English
Pages (from-to)	671-674
Number of pages	3
Journal	Energy & Fuels
Volume	15
DOIs	https://doi.org/10.1021/ef0002086
Publication status	Published - 2001

Keywords

ALUMINOPHOSPHATE MOLECULAR-SIEVES
COPPER-ION
ZEOLITE CATALYSTS
BENZENE
MORDENITE
ACIDITY

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10.1021/ef0002086

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title = "Methylation of Toluene with Methane over ZSM-5 Catalysts",

abstract = "The methylation of toluene with methane in the presence of oxygen over zeolite catalysts is shown to be complicated by extensive disproportionation, hydrodealkylation, and hydrocracking reactions. However, it appears that these undesired reactions can be minimized, to enhance the methylation reaction, by using zeolites with reduced Bronsted acidity.",

keywords = "ALUMINOPHOSPHATE MOLECULAR-SIEVES, COPPER-ION, ZEOLITE CATALYSTS, BENZENE, MORDENITE, ACIDITY",

author = "A. Adebajo and Howe, {Russell Francis} and C. Long",

year = "2001",

doi = "10.1021/ef0002086",

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volume = "15",

pages = "671--674",

journal = "Energy & Fuels",

issn = "0887-0624",

publisher = "American Chemical Society",

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T1 - Methylation of Toluene with Methane over ZSM-5 Catalysts

AU - Adebajo, A.

AU - Howe, Russell Francis

AU - Long, C.

PY - 2001

Y1 - 2001

N2 - The methylation of toluene with methane in the presence of oxygen over zeolite catalysts is shown to be complicated by extensive disproportionation, hydrodealkylation, and hydrocracking reactions. However, it appears that these undesired reactions can be minimized, to enhance the methylation reaction, by using zeolites with reduced Bronsted acidity.

AB - The methylation of toluene with methane in the presence of oxygen over zeolite catalysts is shown to be complicated by extensive disproportionation, hydrodealkylation, and hydrocracking reactions. However, it appears that these undesired reactions can be minimized, to enhance the methylation reaction, by using zeolites with reduced Bronsted acidity.

KW - ALUMINOPHOSPHATE MOLECULAR-SIEVES

KW - COPPER-ION

KW - ZEOLITE CATALYSTS

KW - BENZENE

KW - MORDENITE

KW - ACIDITY

U2 - 10.1021/ef0002086

DO - 10.1021/ef0002086

M3 - Article

SN - 0887-0624

VL - 15

SP - 671

EP - 674

JO - Energy & Fuels

JF - Energy & Fuels

ER -

Methylation of Toluene with Methane over ZSM-5 Catalysts

Abstract

Keywords

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