New Framework Connectivity Patterns in Templated Networks: The Creatinine Zinc Phosphites C4N3OH7·ZnHPO3, C4N3OH7·Zn(H2O)HPO3 and (C4N3OH7)2·ZnHPO3·H2O

William Thomas Alexander Harrison; R. M. Yeates; M. L. F. Phillips; T. M. Nenoff

doi:10.1021/ic020593+

New Framework Connectivity Patterns in Templated Networks: The Creatinine Zinc Phosphites C₄N₃OH₇·ZnHPO₃, C₄N₃OH₇·Zn(H₂O)HPO₃ and (C₄N₃OH₇)₂·ZnHPO₃·H₂O

William Thomas Alexander Harrison, R. M. Yeates, M. L. F. Phillips, T. M. Nenoff

Chemistry

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

The syntheses, crystal structures, and properties of C4N3OH7.ZnHPO3, C4N3OH7.Zn(H2O)HPO3, and (C4N3OH7)(2). ZnHPO3.H2O are reported. These new creatinine zinc phosphites are built up from networks of vertex-sharing HPO3 pseudopyramids and various types of ZnO2N2, ZnO3N, and ZnO2N(H2O) tetrahedra, resulting in extended structures of different dimensionalities (as sheets, clusters, and chains, respectively). They demonstrate the structural effect of incorporating "terminal" (nonnetworking) Zn-N and Zn-OH2 moieties into zinc centers. Crystal data: C4N3OH7.ZnHPO3, triclinic, P1 (No. 2), a = 8.9351(4) Angstrom, b = 9.5011(4) Angstrom, c = 9.9806(4) Angstrom, alpha = 87.451(1)degrees, beta = 85.686(1)degrees, gamma = 89.551(1)degrees, Z = 4; C4N3OH7.Zn(H2O)HPO3, monoclinic, P2(1)/c (No. 14), a = 10.1198(7) Angstrom, b = 7.2996(5) Angstrom, c = 13.7421(9) Angstrom, beta = 107.522(1)degrees, Z = 4; (C4N3OH7)(2).ZnHPO3.H2O, triclinic, P1 (No. 2), a = 10.7289(6) Angstrom, b = 10.9051(6)Angstrom, c = 13.9881(8) Angstrom, alpha = 89.508(1)degrees, beta = 74.995(1)degrees, gamma = 74.932(1)degrees, Z = 4.

Original language	English
Pages (from-to)	1493-1498
Number of pages	5
Journal	Inorganic Chemistry
Volume	42
DOIs	https://doi.org/10.1021/ic020593+
Publication status	Published - 2003

Keywords

HYDROTHERMAL SYNTHESIS
BUILT-UP
PHOSPHATES
TETRAHEDRA
CLUSTER
SOLIDS

Access to Document

10.1021/ic020593+

Cite this

@article{3e7721cb62e54c7a8a1f1fa7757b08f5,

title = "New Framework Connectivity Patterns in Templated Networks: The Creatinine Zinc Phosphites C4N3OH7·ZnHPO3, C4N3OH7·Zn(H2O)HPO3 and (C4N3OH7)2·ZnHPO3·H2O",

abstract = "The syntheses, crystal structures, and properties of C4N3OH7.ZnHPO3, C4N3OH7.Zn(H2O)HPO3, and (C4N3OH7)(2). ZnHPO3.H2O are reported. These new creatinine zinc phosphites are built up from networks of vertex-sharing HPO3 pseudopyramids and various types of ZnO2N2, ZnO3N, and ZnO2N(H2O) tetrahedra, resulting in extended structures of different dimensionalities (as sheets, clusters, and chains, respectively). They demonstrate the structural effect of incorporating {"}terminal{"} (nonnetworking) Zn-N and Zn-OH2 moieties into zinc centers. Crystal data: C4N3OH7.ZnHPO3, triclinic, P1 (No. 2), a = 8.9351(4) Angstrom, b = 9.5011(4) Angstrom, c = 9.9806(4) Angstrom, alpha = 87.451(1)degrees, beta = 85.686(1)degrees, gamma = 89.551(1)degrees, Z = 4; C4N3OH7.Zn(H2O)HPO3, monoclinic, P2(1)/c (No. 14), a = 10.1198(7) Angstrom, b = 7.2996(5) Angstrom, c = 13.7421(9) Angstrom, beta = 107.522(1)degrees, Z = 4; (C4N3OH7)(2).ZnHPO3.H2O, triclinic, P1 (No. 2), a = 10.7289(6) Angstrom, b = 10.9051(6)Angstrom, c = 13.9881(8) Angstrom, alpha = 89.508(1)degrees, beta = 74.995(1)degrees, gamma = 74.932(1)degrees, Z = 4.",

keywords = "HYDROTHERMAL SYNTHESIS, BUILT-UP, PHOSPHATES, TETRAHEDRA, CLUSTER, SOLIDS",

author = "Harrison, {William Thomas Alexander} and Yeates, {R. M.} and Phillips, {M. L. F.} and Nenoff, {T. M.}",

year = "2003",

doi = "10.1021/ic020593+",

language = "English",

volume = "42",

pages = "1493--1498",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

}

TY - JOUR

T1 - New Framework Connectivity Patterns in Templated Networks: The Creatinine Zinc Phosphites C4N3OH7·ZnHPO3, C4N3OH7·Zn(H2O)HPO3 and (C4N3OH7)2·ZnHPO3·H2O

AU - Harrison, William Thomas Alexander

AU - Yeates, R. M.

AU - Phillips, M. L. F.

AU - Nenoff, T. M.

PY - 2003

Y1 - 2003

N2 - The syntheses, crystal structures, and properties of C4N3OH7.ZnHPO3, C4N3OH7.Zn(H2O)HPO3, and (C4N3OH7)(2). ZnHPO3.H2O are reported. These new creatinine zinc phosphites are built up from networks of vertex-sharing HPO3 pseudopyramids and various types of ZnO2N2, ZnO3N, and ZnO2N(H2O) tetrahedra, resulting in extended structures of different dimensionalities (as sheets, clusters, and chains, respectively). They demonstrate the structural effect of incorporating "terminal" (nonnetworking) Zn-N and Zn-OH2 moieties into zinc centers. Crystal data: C4N3OH7.ZnHPO3, triclinic, P1 (No. 2), a = 8.9351(4) Angstrom, b = 9.5011(4) Angstrom, c = 9.9806(4) Angstrom, alpha = 87.451(1)degrees, beta = 85.686(1)degrees, gamma = 89.551(1)degrees, Z = 4; C4N3OH7.Zn(H2O)HPO3, monoclinic, P2(1)/c (No. 14), a = 10.1198(7) Angstrom, b = 7.2996(5) Angstrom, c = 13.7421(9) Angstrom, beta = 107.522(1)degrees, Z = 4; (C4N3OH7)(2).ZnHPO3.H2O, triclinic, P1 (No. 2), a = 10.7289(6) Angstrom, b = 10.9051(6)Angstrom, c = 13.9881(8) Angstrom, alpha = 89.508(1)degrees, beta = 74.995(1)degrees, gamma = 74.932(1)degrees, Z = 4.

AB - The syntheses, crystal structures, and properties of C4N3OH7.ZnHPO3, C4N3OH7.Zn(H2O)HPO3, and (C4N3OH7)(2). ZnHPO3.H2O are reported. These new creatinine zinc phosphites are built up from networks of vertex-sharing HPO3 pseudopyramids and various types of ZnO2N2, ZnO3N, and ZnO2N(H2O) tetrahedra, resulting in extended structures of different dimensionalities (as sheets, clusters, and chains, respectively). They demonstrate the structural effect of incorporating "terminal" (nonnetworking) Zn-N and Zn-OH2 moieties into zinc centers. Crystal data: C4N3OH7.ZnHPO3, triclinic, P1 (No. 2), a = 8.9351(4) Angstrom, b = 9.5011(4) Angstrom, c = 9.9806(4) Angstrom, alpha = 87.451(1)degrees, beta = 85.686(1)degrees, gamma = 89.551(1)degrees, Z = 4; C4N3OH7.Zn(H2O)HPO3, monoclinic, P2(1)/c (No. 14), a = 10.1198(7) Angstrom, b = 7.2996(5) Angstrom, c = 13.7421(9) Angstrom, beta = 107.522(1)degrees, Z = 4; (C4N3OH7)(2).ZnHPO3.H2O, triclinic, P1 (No. 2), a = 10.7289(6) Angstrom, b = 10.9051(6)Angstrom, c = 13.9881(8) Angstrom, alpha = 89.508(1)degrees, beta = 74.995(1)degrees, gamma = 74.932(1)degrees, Z = 4.

KW - HYDROTHERMAL SYNTHESIS

KW - BUILT-UP

KW - PHOSPHATES

KW - TETRAHEDRA

KW - CLUSTER

KW - SOLIDS

U2 - 10.1021/ic020593+

DO - 10.1021/ic020593+

M3 - Article

SN - 0020-1669

VL - 42

SP - 1493

EP - 1498

JO - Inorganic Chemistry

JF - Inorganic Chemistry