Observation of high enantioselectivity for the gas phase hydrogenation of methyl pyruvate using supported Pt catalysts pre-modified with cinchonidine

M  von Arx; N  Dummer; D J  Willock; S H  Taylor; Richard Peter Kerwin Wells; P B  Wells; Graham J. Hutchings

doi:10.1039/b304976k

Observation of high enantioselectivity for the gas phase hydrogenation of methyl pyruvate using supported Pt catalysts pre-modified with cinchonidine

M von Arx, N Dummer, D J Willock, S H Taylor, Richard Peter Kerwin Wells, P B Wells, Graham J. Hutchings

Chemistry

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

Pt supported on alpha-Al2O3, gamma-Al2O3 and SiO2 pre-modified with cinchonidine gives over 50% ee in the hydrogenation of methyl pyruvate to methyl lactate using gas phase reactants at 40 degreesC giving the first clear observation of high enantioselection at the gas/solid interface.

Original language	English
Pages (from-to)	1926-1927
Number of pages	2
Journal	Chemical Communications
Issue number	15
Early online date	27 Jun 2003
DOIs	https://doi.org/10.1039/b304976k
Publication status	Published - Jun 2003

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title = "Observation of high enantioselectivity for the gas phase hydrogenation of methyl pyruvate using supported Pt catalysts pre-modified with cinchonidine",

abstract = "Pt supported on alpha-Al2O3, gamma-Al2O3 and SiO2 pre-modified with cinchonidine gives over 50% ee in the hydrogenation of methyl pyruvate to methyl lactate using gas phase reactants at 40 degreesC giving the first clear observation of high enantioselection at the gas/solid interface.",

author = "{von Arx}, M and N Dummer and Willock, {D J} and Taylor, {S H} and Wells, {Richard Peter Kerwin} and Wells, {P B} and Hutchings, {Graham J.}",

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doi = "10.1039/b304976k",

language = "English",

pages = "1926--1927",

journal = "Chemical Communications",

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T1 - Observation of high enantioselectivity for the gas phase hydrogenation of methyl pyruvate using supported Pt catalysts pre-modified with cinchonidine

AU - von Arx, M

AU - Dummer, N

AU - Willock, D J

AU - Taylor, S H

AU - Wells, Richard Peter Kerwin

AU - Wells, P B

AU - Hutchings, Graham J.

PY - 2003/6

Y1 - 2003/6

N2 - Pt supported on alpha-Al2O3, gamma-Al2O3 and SiO2 pre-modified with cinchonidine gives over 50% ee in the hydrogenation of methyl pyruvate to methyl lactate using gas phase reactants at 40 degreesC giving the first clear observation of high enantioselection at the gas/solid interface.

AB - Pt supported on alpha-Al2O3, gamma-Al2O3 and SiO2 pre-modified with cinchonidine gives over 50% ee in the hydrogenation of methyl pyruvate to methyl lactate using gas phase reactants at 40 degreesC giving the first clear observation of high enantioselection at the gas/solid interface.

U2 - 10.1039/b304976k

DO - 10.1039/b304976k

M3 - Article

SN - 1359-7345

SP - 1926

EP - 1927

JO - Chemical Communications

JF - Chemical Communications

IS - 15

ER -

Observation of high enantioselectivity for the gas phase hydrogenation of methyl pyruvate using supported Pt catalysts pre-modified with cinchonidine

Abstract

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