Poly[3-methyl­pyridinium [(μ2-di­hydrogen phosphito)bis­(μ3-hydrogen phosphito)dizinc]]

Jago G. Love-Jennings; Aidan P. McKay; David B. Cordes; William T. A. Harrison

doi:10.1107/S2414314624003456

Poly[3-methylpyridinium [(μ2-dihydrogen phosphito)bis(μ3-hydrogen phosphito)dizinc]]

Jago G. Love-Jennings
, Aidan P. McKay
, David B. Cordes
, William T. A. Harrison^* (Corresponding Author)

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

In the title compound, {(C6H8N)[Zn2(HPO3)2(H2PO3)]}n, the constituent ZnO4, HPO3 and H2PO3 polyhedra of the inorganic component are linked into (010) sheets by Zn—O—P bonds (mean angle = 134.4°) and the layers are reinforced by O—H⋯O hydrogen bonds. The protonated templates are anchored to the inorganic sheets via bifurcated N—H⋯(O,O) hydrogen bonds.

Original language	English
Article number	x240345
Number of pages	7
Journal	IUCrData
Volume	9
Issue number	4
Early online date	26 Apr 2024
DOIs	https://doi.org/10.1107/S2414314624003456
Publication status	Published - Apr 2024

Keywords

crystal structure
zincophosphite
layered structure
bifurcated hydrogen bond

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Love-Jennings_etal_IUCrD_Ply_3_Methyl_VoR
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Cite this

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title = "Poly[3-methylpyridinium [(μ2-dihydrogen phosphito)bis(μ3-hydrogen phosphito)dizinc]]",

abstract = "In the title compound, \{(C6H8N)[Zn2(HPO3)2(H2PO3)]\}n, the constituent ZnO4, HPO3 and H2PO3 polyhedra of the inorganic component are linked into (010) sheets by Zn—O—P bonds (mean angle = 134.4°) and the layers are reinforced by O—H⋯O hydrogen bonds. The protonated templates are anchored to the inorganic sheets via bifurcated N—H⋯(O,O) hydrogen bonds.",

keywords = "crystal structure, zincophosphite, layered structure, bifurcated hydrogen bond",

author = "Love-Jennings, \{Jago G.\} and McKay, \{Aidan P.\} and Cordes, \{David B.\} and Harrison, \{William T. A.\}",

year = "2024",

month = apr,

doi = "10.1107/S2414314624003456",

language = "English",

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T1 - Poly[3-methylpyridinium [(μ2-dihydrogen phosphito)bis(μ3-hydrogen phosphito)dizinc]]

AU - Love-Jennings, Jago G.

AU - McKay, Aidan P.

AU - Cordes, David B.

AU - Harrison, William T. A.

PY - 2024/4

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N2 - In the title compound, {(C6H8N)[Zn2(HPO3)2(H2PO3)]}n, the constituent ZnO4, HPO3 and H2PO3 polyhedra of the inorganic component are linked into (010) sheets by Zn—O—P bonds (mean angle = 134.4°) and the layers are reinforced by O—H⋯O hydrogen bonds. The protonated templates are anchored to the inorganic sheets via bifurcated N—H⋯(O,O) hydrogen bonds.

AB - In the title compound, {(C6H8N)[Zn2(HPO3)2(H2PO3)]}n, the constituent ZnO4, HPO3 and H2PO3 polyhedra of the inorganic component are linked into (010) sheets by Zn—O—P bonds (mean angle = 134.4°) and the layers are reinforced by O—H⋯O hydrogen bonds. The protonated templates are anchored to the inorganic sheets via bifurcated N—H⋯(O,O) hydrogen bonds.

KW - crystal structure

KW - zincophosphite

KW - layered structure

KW - bifurcated hydrogen bond

U2 - 10.1107/S2414314624003456

DO - 10.1107/S2414314624003456

M3 - Article

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