Structural characterization of a new copper(II) complex of 1,10-phenanthroline and benzoate [Cu(phen)(C6H5CO (2) (-) )(2)]

S. S. Batool; S. Ahmad; I. U. Khan; Missing Ejaz; W. T. A. Harrison

doi:10.1134/S0022476615020286

Structural characterization of a new copper(II) complex of 1,10-phenanthroline and benzoate [Cu(phen)(C6H5CO (2) (-) )(2)]

S. S. Batool^*, S. Ahmad, I. U. Khan, Missing Ejaz, W. T. A. Harrison

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

A new mixed-ligand copper(II) complex of 1,10-phenanthroline (phen) and benzoate ligands having the general formula [Cu(phen)(C6H5CO2)(2)] is prepared and its crystal structure is determined by X-ray crystallography. The complex exists in the monomeric form; the coordination environment around the copper(II) ion is square planar, with the pair of monodentate benzoate ligands being in a cis disposition. In the crystal, the molecules are linked into [001] chains by weak C-Ha

Original language	English
Pages (from-to)	387-391
Number of pages	5
Journal	Journal of Structural Chemistry
Volume	56
Issue number	2
DOIs	https://doi.org/10.1134/S0022476615020286
Publication status	Published - Mar 2015

Keywords

copper(II) carboxylates
1, 10-phenanthroline
benzoic acid
ray crystal-structures
magnetic-properties
superoxide-dismutase
DNA cleavage
acid
ligands
benzimidazole
coordination
biochemistry
monohydrate

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title = "Structural characterization of a new copper(II) complex of 1,10-phenanthroline and benzoate [Cu(phen)(C6H5CO (2) (-) )(2)]",

abstract = "A new mixed-ligand copper(II) complex of 1,10-phenanthroline (phen) and benzoate ligands having the general formula [Cu(phen)(C6H5CO2)(2)] is prepared and its crystal structure is determined by X-ray crystallography. The complex exists in the monomeric form; the coordination environment around the copper(II) ion is square planar, with the pair of monodentate benzoate ligands being in a cis disposition. In the crystal, the molecules are linked into [001] chains by weak C-Ha",

keywords = "copper(II) carboxylates, 1, 10-phenanthroline, benzoic acid, ray crystal-structures, magnetic-properties, superoxide-dismutase, DNA cleavage, acid, ligands, benzimidazole, coordination, biochemistry, monohydrate",

author = "Batool, {S. S.} and S. Ahmad and Khan, {I. U.} and Missing Ejaz and Harrison, {W. T. A.}",

year = "2015",

month = mar,

doi = "10.1134/S0022476615020286",

language = "English",

volume = "56",

pages = "387--391",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "MAIK NAUKA/INTERPERIODICA/SPRINGER",

number = "2",

}

TY - JOUR

T1 - Structural characterization of a new copper(II) complex of 1,10-phenanthroline and benzoate [Cu(phen)(C6H5CO (2) (-) )(2)]

AU - Batool, S. S.

AU - Ahmad, S.

AU - Khan, I. U.

AU - Ejaz, Missing

AU - Harrison, W. T. A.

PY - 2015/3

Y1 - 2015/3

N2 - A new mixed-ligand copper(II) complex of 1,10-phenanthroline (phen) and benzoate ligands having the general formula [Cu(phen)(C6H5CO2)(2)] is prepared and its crystal structure is determined by X-ray crystallography. The complex exists in the monomeric form; the coordination environment around the copper(II) ion is square planar, with the pair of monodentate benzoate ligands being in a cis disposition. In the crystal, the molecules are linked into [001] chains by weak C-Ha

AB - A new mixed-ligand copper(II) complex of 1,10-phenanthroline (phen) and benzoate ligands having the general formula [Cu(phen)(C6H5CO2)(2)] is prepared and its crystal structure is determined by X-ray crystallography. The complex exists in the monomeric form; the coordination environment around the copper(II) ion is square planar, with the pair of monodentate benzoate ligands being in a cis disposition. In the crystal, the molecules are linked into [001] chains by weak C-Ha

KW - copper(II) carboxylates

KW - 1, 10-phenanthroline

KW - benzoic acid

KW - ray crystal-structures

KW - magnetic-properties

KW - superoxide-dismutase

KW - DNA cleavage

KW - acid

KW - ligands

KW - benzimidazole

KW - coordination

KW - biochemistry

KW - monohydrate

U2 - 10.1134/S0022476615020286

DO - 10.1134/S0022476615020286

M3 - Article

SN - 0022-4766

VL - 56

SP - 387

EP - 391

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

IS - 2

ER -

Structural characterization of a new copper(II) complex of 1,10-phenanthroline and benzoate [Cu(phen)(C6H5CO (2) (-) )(2)]

Abstract

Keywords

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