The first metal complex with the hydrazine dicarboxylate dianion: Na-2(O2CNHNHCO2)(H2O)(3)

Krishnan Srinivasan; Subbaiah Govindarajan; William Thomas Alexander Harrison

doi:10.1016/j.inoche.2006.06.018

The first metal complex with the hydrazine dicarboxylate dianion: Na-2(O2CNHNHCO2)(H2O)(3)

Krishnan Srinivasan, Subbaiah Govindarajan, William Thomas Alexander Harrison

Chemistry

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1 Citation (Scopus)

Abstract

The title compound is the first complex of a metal ion with the hydrazinedicarboxylate dianion. One of the sodium cations is coordinated by two N,O-bidenate and two O-monodentate ligands to result in distorted trans-NaN2O4 octahedra. Crystal data: Na-2(O2CNHNHCO2) center dot 3H(2)O, M-r = 218.08, triclinic, P (1) over bar (No. 2), a = 5.5123 (2) angstrom, b = 8.7311 (3) angstrom, c = 8.8117 (3) angstrom, alpha = 107.005 (2)degrees, beta = 99.431 (2)degrees, gamma = 101.552 (2)degrees, V= 385.98 (2) angstrom(3), Z = 2, R(F) = 0.027, wR(F-2) = 0.092. (C) 2006 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	1117-1120
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	9
Issue number	11
Early online date	30 Jun 2006
DOIs	https://doi.org/10.1016/j.inoche.2006.06.018
Publication status	Published - Nov 2006

Keywords

ligand
sodium
crystal structure
molecular structure
derivatives
crystal

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10.1016/j.inoche.2006.06.018

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title = "The first metal complex with the hydrazine dicarboxylate dianion: Na-2(O2CNHNHCO2)(H2O)(3)",

abstract = "The title compound is the first complex of a metal ion with the hydrazinedicarboxylate dianion. One of the sodium cations is coordinated by two N,O-bidenate and two O-monodentate ligands to result in distorted trans-NaN2O4 octahedra. Crystal data: Na-2(O2CNHNHCO2) center dot 3H(2)O, M-r = 218.08, triclinic, P (1) over bar (No. 2), a = 5.5123 (2) angstrom, b = 8.7311 (3) angstrom, c = 8.8117 (3) angstrom, alpha = 107.005 (2)degrees, beta = 99.431 (2)degrees, gamma = 101.552 (2)degrees, V= 385.98 (2) angstrom(3), Z = 2, R(F) = 0.027, wR(F-2) = 0.092. (C) 2006 Elsevier B.V. All rights reserved.",

keywords = "ligand, sodium, crystal structure, molecular structure, derivatives, crystal",

author = "Krishnan Srinivasan and Subbaiah Govindarajan and Harrison, {William Thomas Alexander}",

year = "2006",

month = nov,

doi = "10.1016/j.inoche.2006.06.018",

language = "English",

volume = "9",

pages = "1117--1120",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier BV",

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TY - JOUR

T1 - The first metal complex with the hydrazine dicarboxylate dianion: Na-2(O2CNHNHCO2)(H2O)(3)

AU - Srinivasan, Krishnan

AU - Govindarajan, Subbaiah

AU - Harrison, William Thomas Alexander

PY - 2006/11

Y1 - 2006/11

N2 - The title compound is the first complex of a metal ion with the hydrazinedicarboxylate dianion. One of the sodium cations is coordinated by two N,O-bidenate and two O-monodentate ligands to result in distorted trans-NaN2O4 octahedra. Crystal data: Na-2(O2CNHNHCO2) center dot 3H(2)O, M-r = 218.08, triclinic, P (1) over bar (No. 2), a = 5.5123 (2) angstrom, b = 8.7311 (3) angstrom, c = 8.8117 (3) angstrom, alpha = 107.005 (2)degrees, beta = 99.431 (2)degrees, gamma = 101.552 (2)degrees, V= 385.98 (2) angstrom(3), Z = 2, R(F) = 0.027, wR(F-2) = 0.092. (C) 2006 Elsevier B.V. All rights reserved.

AB - The title compound is the first complex of a metal ion with the hydrazinedicarboxylate dianion. One of the sodium cations is coordinated by two N,O-bidenate and two O-monodentate ligands to result in distorted trans-NaN2O4 octahedra. Crystal data: Na-2(O2CNHNHCO2) center dot 3H(2)O, M-r = 218.08, triclinic, P (1) over bar (No. 2), a = 5.5123 (2) angstrom, b = 8.7311 (3) angstrom, c = 8.8117 (3) angstrom, alpha = 107.005 (2)degrees, beta = 99.431 (2)degrees, gamma = 101.552 (2)degrees, V= 385.98 (2) angstrom(3), Z = 2, R(F) = 0.027, wR(F-2) = 0.092. (C) 2006 Elsevier B.V. All rights reserved.

KW - ligand

KW - sodium

KW - crystal structure

KW - molecular structure

KW - derivatives

KW - crystal

U2 - 10.1016/j.inoche.2006.06.018

DO - 10.1016/j.inoche.2006.06.018

M3 - Article

SN - 1387-7003

VL - 9

SP - 1117

EP - 1120

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 11

ER -

The first metal complex with the hydrazine dicarboxylate dianion: Na-2(O2CNHNHCO2)(H2O)(3)

Abstract

Keywords

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