Abstract
The title compound is the first complex of a metal ion with the hydrazinedicarboxylate dianion. One of the sodium cations is coordinated by two N,O-bidenate and two O-monodentate ligands to result in distorted trans-NaN2O4 octahedra. Crystal data: Na-2(O2CNHNHCO2) center dot 3H(2)O, M-r = 218.08, triclinic, P (1) over bar (No. 2), a = 5.5123 (2) angstrom, b = 8.7311 (3) angstrom, c = 8.8117 (3) angstrom, alpha = 107.005 (2)degrees, beta = 99.431 (2)degrees, gamma = 101.552 (2)degrees, V= 385.98 (2) angstrom(3), Z = 2, R(F) = 0.027, wR(F-2) = 0.092. (C) 2006 Elsevier B.V. All rights reserved.
| Original language | English |
|---|---|
| Pages (from-to) | 1117-1120 |
| Number of pages | 4 |
| Journal | Inorganic Chemistry Communications |
| Volume | 9 |
| Issue number | 11 |
| Early online date | 30 Jun 2006 |
| DOIs | |
| Publication status | Published - Nov 2006 |
Keywords
- ligand
- sodium
- crystal structure
- molecular structure
- derivatives
- crystal
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