2-[(E)-2-(3,4-Dichlorobenzylidene)hydrazin-1-yl]quinoxaline

Thais C. M. Noguiera; Alexandra C. Pinheiro; Marcus V. N. De Souza; James L. Wardell; Edward R. T. Tiekink

doi:10.1107/S1600536814000415

2-[(E)-2-(3,4-Dichlorobenzylidene)hydrazin-1-yl]quinoxaline

Thais C. M. Noguiera, Alexandra C. Pinheiro, Marcus V. N. De Souza, James L. Wardell, Edward R. T. Tiekink

Research output: Contribution to journal › Article › peer-review

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Abstract

The 21 non-H atoms of the title compound, C15H10Cl2N4, are almost planar (r.m.s. deviation = 0.032Å); the conformation about the N=C bond [1.277(6)Å] is E. In the crystal, zigzag supramolecular chains along the c axis (glide symmetry) are formed via N - HN hydrogen bonds. These associate along the b axis by π-π interactions between the fused and terminal benzene rings [intercentroid distance = 3.602(3)Å] so that layers form in the bc plane.

Original language	English
Pages (from-to)	o125-o125
Number of pages	1
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	70
Issue number	2
Early online date	11 Jan 2014
DOIs	https://doi.org/10.1107/S1600536814000415
Publication status	Published - Feb 2014

Bibliographical note

The use of the EPSRC X-ray crystallographic service (Coles & Gale, 2012[Coles, S. J. & Gale, P. A. (2012). Chem. Sci, 3, 683-689.]) at the University of Southampton, England, and the valuable assistance of the staff there is gratefully acknowledged. JLW acknowledges support from CAPES (Brazil). Structural studies are supported by the Ministry of Higher Education (Malaysia) and the University of Malaya through the High-Impact Research scheme (UM.C/HIR/MOHE/SC/3).

Keywords

data-to-parameter ratio = 12.4
mean σ(C-C) = 0.007 Å
R factor = 0.060
single-crystal X-ray study
T = 120 K
wR factor = 0.219

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2-[(E)-2-(3,4-Dichlorobenzylidene)- hydrazin-1-yl]quinoxaline
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Cite this

@article{8938aa91f2684af2984cf2421b972170,

title = "2-[(E)-2-(3,4-Dichlorobenzylidene)hydrazin-1-yl]quinoxaline",

abstract = "The 21 non-H atoms of the title compound, C15H10Cl2N4, are almost planar (r.m.s. deviation = 0.032{\AA}); the conformation about the N=C bond [1.277(6){\AA}] is E. In the crystal, zigzag supramolecular chains along the c axis (glide symmetry) are formed via N - HN hydrogen bonds. These associate along the b axis by π-π interactions between the fused and terminal benzene rings [intercentroid distance = 3.602(3){\AA}] so that layers form in the bc plane.",

keywords = "data-to-parameter ratio = 12.4, mean σ(C-C) = 0.007 {\AA}, R factor = 0.060, single-crystal X-ray study, T = 120 K, wR factor = 0.219",

author = "Noguiera, {Thais C. M.} and Pinheiro, {Alexandra C.} and {De Souza}, {Marcus V. N.} and Wardell, {James L.} and Tiekink, {Edward R. T.}",

note = "The use of the EPSRC X-ray crystallographic service (Coles & Gale, 2012[Coles, S. J. & Gale, P. A. (2012). Chem. Sci, 3, 683-689.]) at the University of Southampton, England, and the valuable assistance of the staff there is gratefully acknowledged. JLW acknowledges support from CAPES (Brazil). Structural studies are supported by the Ministry of Higher Education (Malaysia) and the University of Malaya through the High-Impact Research scheme (UM.C/HIR/MOHE/SC/3).",

year = "2014",

month = feb,

doi = "10.1107/S1600536814000415",

language = "English",

volume = "70",

pages = "o125--o125",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "2",

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TY - JOUR

T1 - 2-[(E)-2-(3,4-Dichlorobenzylidene)hydrazin-1-yl]quinoxaline

AU - Noguiera, Thais C. M.

AU - Pinheiro, Alexandra C.

AU - De Souza, Marcus V. N.

AU - Wardell, James L.

AU - Tiekink, Edward R. T.

N1 - The use of the EPSRC X-ray crystallographic service (Coles & Gale, 2012[Coles, S. J. & Gale, P. A. (2012). Chem. Sci, 3, 683-689.]) at the University of Southampton, England, and the valuable assistance of the staff there is gratefully acknowledged. JLW acknowledges support from CAPES (Brazil). Structural studies are supported by the Ministry of Higher Education (Malaysia) and the University of Malaya through the High-Impact Research scheme (UM.C/HIR/MOHE/SC/3).

PY - 2014/2

Y1 - 2014/2

N2 - The 21 non-H atoms of the title compound, C15H10Cl2N4, are almost planar (r.m.s. deviation = 0.032Å); the conformation about the N=C bond [1.277(6)Å] is E. In the crystal, zigzag supramolecular chains along the c axis (glide symmetry) are formed via N - HN hydrogen bonds. These associate along the b axis by π-π interactions between the fused and terminal benzene rings [intercentroid distance = 3.602(3)Å] so that layers form in the bc plane.

AB - The 21 non-H atoms of the title compound, C15H10Cl2N4, are almost planar (r.m.s. deviation = 0.032Å); the conformation about the N=C bond [1.277(6)Å] is E. In the crystal, zigzag supramolecular chains along the c axis (glide symmetry) are formed via N - HN hydrogen bonds. These associate along the b axis by π-π interactions between the fused and terminal benzene rings [intercentroid distance = 3.602(3)Å] so that layers form in the bc plane.

KW - data-to-parameter ratio = 12.4

KW - mean σ(C-C) = 0.007 Å

KW - R factor = 0.060

KW - single-crystal X-ray study

KW - T = 120 K

KW - wR factor = 0.219

UR - http://www.scopus.com/inward/record.url?scp=84893637596&partnerID=8YFLogxK

U2 - 10.1107/S1600536814000415

DO - 10.1107/S1600536814000415

M3 - Article

AN - SCOPUS:84893637596

SN - 1600-5368

VL - 70

SP - o125-o125

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 2

ER -

2-[(E)-2-(3,4-Dichlorobenzylidene)hydrazin-1-yl]quinoxaline

Abstract

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Keywords

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