7-Chloro-4-(2-hydroxyethylamino)quinolin-1-ium chloride

Ivson L. Gama; Marcus V. N. De Souza; James L. Wardell; Edward R. T. Tiekink

doi:10.1107/S1600536814004565

7-Chloro-4-(2-hydroxyethylamino)quinolin-1-ium chloride

Ivson L. Gama, Marcus V. N. De Souza, James L. Wardell, Edward R. T. Tiekink

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Abstract

In the title salt, C₁₁H₁₂ClN₂O ⁺·Cl^-, the ten non-H atoms comprising the quinolinium residue are coplanar (r.m.s. deviation = 0.041Å) and the hydroxyethyl group is approximately perpendicular to this plane [Cring-N-Cmethylene-C torsion angle =-74.61(18)°]. A supramolecular chain aligned along [101] mediated by charge-assisted O/N-H..Cl^- hydrogen bonds features in the crystal packing. Chains are connected into a three-dimensional architecture by C-H..O(hydroxy) interactions.

Original language	English
Pages (from-to)	o385-o386
Number of pages	2
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	70
Issue number	4
Early online date	5 Mar 2014
DOIs	https://doi.org/10.1107/S1600536814004565
Publication status	Published - Apr 2014

Bibliographical note

The use of the EPSRC X-ray crystallographic service at the University of Southampton, England [Coles, S. J. & Gale, P. A. (2012). Chem. Sci. 3, 683-689.]), and the valuable assistance of the staff there is gratefully acknowledged. JLW acknowledges support from CAPES (Brazil). Structural studies are supported by the Ministry of Higher Education (Malaysia) and the University of Malaya through the High-Impact Research scheme (UM·C/HIR/MOHE/SC/3).

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7-Chloro-4-(2-hydroxyethylamino)- quinolin-1-ium chloride
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@article{ecf34e7a0ef947c8ae1f1103f18854e3,

title = "7-Chloro-4-(2-hydroxyethylamino)quinolin-1-ium chloride",

abstract = "In the title salt, C11H12ClN2O +·Cl-, the ten non-H atoms comprising the quinolinium residue are coplanar (r.m.s. deviation = 0.041{\AA}) and the hydroxyethyl group is approximately perpendicular to this plane [Cring-N-Cmethylene-C torsion angle =-74.61(18)°]. A supramolecular chain aligned along [101] mediated by charge-assisted O/N-H..Cl- hydrogen bonds features in the crystal packing. Chains are connected into a three-dimensional architecture by C-H..O(hydroxy) interactions.",

author = "Gama, {Ivson L.} and {De Souza}, {Marcus V. N.} and Wardell, {James L.} and Tiekink, {Edward R. T.}",

note = "The use of the EPSRC X-ray crystallographic service at the University of Southampton, England [Coles, S. J. & Gale, P. A. (2012). Chem. Sci. 3, 683-689.]), and the valuable assistance of the staff there is gratefully acknowledged. JLW acknowledges support from CAPES (Brazil). Structural studies are supported by the Ministry of Higher Education (Malaysia) and the University of Malaya through the High-Impact Research scheme (UM·C/HIR/MOHE/SC/3).",

year = "2014",

month = apr,

doi = "10.1107/S1600536814004565",

language = "English",

volume = "70",

pages = "o385--o386",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "4",

}

TY - JOUR

T1 - 7-Chloro-4-(2-hydroxyethylamino)quinolin-1-ium chloride

AU - Gama, Ivson L.

AU - De Souza, Marcus V. N.

AU - Wardell, James L.

AU - Tiekink, Edward R. T.

N1 - The use of the EPSRC X-ray crystallographic service at the University of Southampton, England [Coles, S. J. & Gale, P. A. (2012). Chem. Sci. 3, 683-689.]), and the valuable assistance of the staff there is gratefully acknowledged. JLW acknowledges support from CAPES (Brazil). Structural studies are supported by the Ministry of Higher Education (Malaysia) and the University of Malaya through the High-Impact Research scheme (UM·C/HIR/MOHE/SC/3).

PY - 2014/4

Y1 - 2014/4

N2 - In the title salt, C11H12ClN2O +·Cl-, the ten non-H atoms comprising the quinolinium residue are coplanar (r.m.s. deviation = 0.041Å) and the hydroxyethyl group is approximately perpendicular to this plane [Cring-N-Cmethylene-C torsion angle =-74.61(18)°]. A supramolecular chain aligned along [101] mediated by charge-assisted O/N-H..Cl- hydrogen bonds features in the crystal packing. Chains are connected into a three-dimensional architecture by C-H..O(hydroxy) interactions.

AB - In the title salt, C11H12ClN2O +·Cl-, the ten non-H atoms comprising the quinolinium residue are coplanar (r.m.s. deviation = 0.041Å) and the hydroxyethyl group is approximately perpendicular to this plane [Cring-N-Cmethylene-C torsion angle =-74.61(18)°]. A supramolecular chain aligned along [101] mediated by charge-assisted O/N-H..Cl- hydrogen bonds features in the crystal packing. Chains are connected into a three-dimensional architecture by C-H..O(hydroxy) interactions.

UR - http://www.scopus.com/inward/record.url?scp=84898749968&partnerID=8YFLogxK

U2 - 10.1107/S1600536814004565

DO - 10.1107/S1600536814004565

M3 - Article

AN - SCOPUS:84898749968

SN - 1600-5368

VL - 70

SP - o385-o386

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

7-Chloro-4-(2-hydroxyethylamino)quinolin-1-ium chloride

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