Advective pore-water transport of hydrocarbons in North East Scotland coastal sands

Luis J Perez Calderon* (Corresponding Author), Kathrin Vossen, Lloyd D Potts, Alejandro Gallego, James A Anderson, Ursula Witte

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)


Oil spills in the marine environment can cause ecosystem-level impacts. Dispersant application as an oil spill response measure leads to the widespread distribution of hydrocarbons in the water column and marine sediments. The North Sea is an area of intense hydrocarbon production and is at risk of oil spills, which are of concern to its benthic ecosystem due to its sediments’ high permeability. Here, entrainment of hydrocarbons via pore-water advection into permeable North Sea sands and the associated effect of Superdispersant-25, a commercial oil dispersant, were evaluated in a laboratory. Centrally stirred chambers that induce advective pore-water fluxes in sediments were filled with sediment, seawater and mixtures of oil and Superdispersant-25. Dispersant application had contrasting effects on hydrocarbon interactions with sediment: (1) it reduced accumulation of hydrocarbons in surface sediments and (2) facilitated the entrainment of hydrocarbons up to 8 cm deep into sediments by increasing hydrocarbon solubility in seawater and its subsequent washout or pumping into sediment by pore-water movement. Results here show that dispersant application can have counter-intuitive effects on hydrocarbon interactions with marine sediments and highlight the need for further research in this area to make better informed decision in an oil spill response scenario.
Original languageEnglish
Pages (from-to)28445-28459
Number of pages14
JournalEnvironmental Science and Pollution Research
Issue number28
Early online date7 Aug 2018
Publication statusPublished - 31 Oct 2018

Bibliographical note

LJP and hydrocarbon analytics were funded through MarCRF funds for a PhD project designed by UW, JA and AG and awarded to LJP.

Electronic supplementary material: The online version of this article ( contains supplementary material, which is available to authorized users.


  • Advection
  • Seabed
  • Oil
  • Dispersant
  • Oil entrainment
  • Advective pore-water transport
  • Marine pollution
  • Hydrocarbons


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