Barsilowsky's base and Perkin's base: two products from the oxidation of p-toluidine

M. John Plater; William T. A. Harrison

doi:10.3184/174751914X13995700264041

Barsilowsky's base and Perkin's base: two products from the oxidation of p-toluidine

M. John Plater, William T. A. Harrison

Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

9 Downloads (Pure)

Abstract

The oxidation of p-toluidine in H+/H2O can give mainly a tetramer, a trimer, or a mixture of both. The outcome is dependent upon the oxidant, the pH and the concentration ofp-toluidine. Both the trimer and tetramer are definitively characterised by X-ray single crystal structure determination.

Original language	English
Pages (from-to)	351-355
Number of pages	5
Journal	Journal of Chemical Research
Volume	38
Issue number	6
DOIs	https://doi.org/10.3184/174751914X13995700264041
Publication status	Published - 1 Jun 2014

Bibliographical note

Acknowledgements
We are grateful to the UK EPSRC national mass spectrometry service center for mass spectra.

Keywords

Barsilowsky's base
p-toluidine
Perkins's base
potassium dichromate
potassium permanganate

Access to Document

10.3184/174751914X13995700264041

JCR Barsilowsky vs Perkin REVISED MS
This is the author's accepted manuscript of an article published in the Journal of Chemical Research
Accepted author manuscript, 310 KB

Cite this

@article{b99e33da0ed543b4843f7f6a2be205ad,

title = "Barsilowsky's base and Perkin's base: two products from the oxidation of p-toluidine ",

abstract = "The oxidation of p-toluidine in H+/H2O can give mainly a tetramer, a trimer, or a mixture of both. The outcome is dependent upon the oxidant, the pH and the concentration ofp-toluidine. Both the trimer and tetramer are definitively characterised by X-ray single crystal structure determination. ",

keywords = "Barsilowsky's base, p-toluidine, Perkins's base, potassium dichromate, potassium permanganate",

author = "Plater, {M. John} and Harrison, {William T. A.}",

note = "Acknowledgements We are grateful to the UK EPSRC national mass spectrometry service center for mass spectra. ",

year = "2014",

month = jun,

day = "1",

doi = "10.3184/174751914X13995700264041",

language = "English",

volume = "38",

pages = "351--355",

journal = "Journal of Chemical Research",

issn = "0308-2342",

publisher = "Science Reviews Ltd",

number = "6",

}

TY - JOUR

T1 - Barsilowsky's base and Perkin's base

T2 - two products from the oxidation of p-toluidine

AU - Plater, M. John

AU - Harrison, William T. A.

N1 - Acknowledgements We are grateful to the UK EPSRC national mass spectrometry service center for mass spectra.

PY - 2014/6/1

Y1 - 2014/6/1

N2 - The oxidation of p-toluidine in H+/H2O can give mainly a tetramer, a trimer, or a mixture of both. The outcome is dependent upon the oxidant, the pH and the concentration ofp-toluidine. Both the trimer and tetramer are definitively characterised by X-ray single crystal structure determination.

AB - The oxidation of p-toluidine in H+/H2O can give mainly a tetramer, a trimer, or a mixture of both. The outcome is dependent upon the oxidant, the pH and the concentration ofp-toluidine. Both the trimer and tetramer are definitively characterised by X-ray single crystal structure determination.

KW - Barsilowsky's base

KW - p-toluidine

KW - Perkins's base

KW - potassium dichromate

KW - potassium permanganate

U2 - 10.3184/174751914X13995700264041

DO - 10.3184/174751914X13995700264041

M3 - Article

SN - 0308-2342

VL - 38

SP - 351

EP - 355

JO - Journal of Chemical Research

JF - Journal of Chemical Research

IS - 6

ER -

Barsilowsky's base and Perkin's base: two products from the oxidation of p-toluidine

Abstract

Bibliographical note

Keywords

Access to Document

Fingerprint

Cite this