Bis(triethanolamine-N,O,O')nickel(II) bis(saccharinate)

Y. Topcu, O. Andac, V. T. Yilmaz, William Thomas Alexander Harrison

Research output: Contribution to journalArticlepeer-review

21 Citations (Web of Science)

Abstract

The structure of the title compound, [Ni(C6H15NO3)(2)](C7H4NO3S)(2), consists of a cationic [Ni(TEA)(2)](2+) and two anionic (SAC)(-) moieties (TEA is triethanolamine and SAC is the saccharinate anion). Two TEA ligands coordinate to the NiII ion through four O atoms and two N atoms acting as tridentate ligands (N,O,O') in a distorted octahedral environment, with the bond distances [d(Ni-O) = 2.078 (2) and 2.082 (2) Angstrom, and d(Ni-N) = 2.108 (2) Angstrom]. SAC anions participate in intermolecular hydrogen bonding with the hydroxyl H atoms of the TEA ligands to form a three-dimensional network.

Original languageEnglish
Pages (from-to)m82-m84
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
VolumeE57
DOIs
Publication statusPublished - 2001

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