Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis-(pyridin-4-yl)pentane linkers

William T. A. Harrison; M. John Plater; Benjamin M. De Silva; Mark R. St J. Foreman

doi:10.1107/S1600536814014779

Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis-(pyridin-4-yl)pentane linkers

William T. A. Harrison, M. John Plater, Benjamin M. De Silva, Mark R. St J. Foreman

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, poly[[di-aqua-bis-[1,5-bis-(pyridin-4-yl)pentane-κ(2) N:N']cadmium] bis-(perchlorate) 1,5-bis-(pyridin-4-yl)pentane ethanol mono-solvate], [Cd(C15H18N2)2(H2O)2](ClO4)2·C15H18N2·C2H6O, is a layered coordination polymer built up from highly squashed 4(4) nets in which the octa-hedral trans-CdO2N4 nodes (Cd site symmetry -1) are linked by the bifunctional ligands, forming infinite (110) sheets. The cationic sheets are charge-balanced by inter-layer perchlorate ions. A free 1,5-bis-(pyridin-4-yl)pentane mol-ecule and an ethanol mol-ecule of crystallization are also found in the inter-sheet region. A number of O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds help to consolidate the layered structure.

Original language	English
Pages (from-to)	80-83
Number of pages	4
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	70
Issue number	8
Early online date	31 Jul 2014
DOIs	https://doi.org/10.1107/S1600536814014779
Publication status	Published - 1 Aug 2014

Bibliographical note

Acknowledgements

We thank the EPSRC National Crystallography Service (University of Southampton) for the data collection.

Keywords

Cadmium
Flexible ligand
Layered coordination polymer
crystal structure

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Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis-(pyridin-4-yl)pentane linkers. / Harrison, William T. A.; Plater, M. John; De Silva, Benjamin M. et al.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 70, No. 8, 01.08.2014, p. 80-83.

Research output: Contribution to journal › Article › peer-review

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title = "Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis-(pyridin-4-yl)pentane linkers",

abstract = "The title compound, poly[[di-aqua-bis-[1,5-bis-(pyridin-4-yl)pentane-κ(2) N:N']cadmium] bis-(perchlorate) 1,5-bis-(pyridin-4-yl)pentane ethanol mono-solvate], [Cd(C15H18N2)2(H2O)2](ClO4)2·C15H18N2·C2H6O, is a layered coordination polymer built up from highly squashed 4(4) nets in which the octa-hedral trans-CdO2N4 nodes (Cd site symmetry -1) are linked by the bifunctional ligands, forming infinite (110) sheets. The cationic sheets are charge-balanced by inter-layer perchlorate ions. A free 1,5-bis-(pyridin-4-yl)pentane mol-ecule and an ethanol mol-ecule of crystallization are also found in the inter-sheet region. A number of O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds help to consolidate the layered structure.",

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author = "Harrison, {William T. A.} and Plater, {M. John} and {De Silva}, {Benjamin M.} and Foreman, {Mark R. St J.}",

note = "Acknowledgements We thank the EPSRC National Crystallography Service (University of Southampton) for the data collection.",

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AU - De Silva, Benjamin M.

AU - Foreman, Mark R. St J.

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N2 - The title compound, poly[[di-aqua-bis-[1,5-bis-(pyridin-4-yl)pentane-κ(2) N:N']cadmium] bis-(perchlorate) 1,5-bis-(pyridin-4-yl)pentane ethanol mono-solvate], [Cd(C15H18N2)2(H2O)2](ClO4)2·C15H18N2·C2H6O, is a layered coordination polymer built up from highly squashed 4(4) nets in which the octa-hedral trans-CdO2N4 nodes (Cd site symmetry -1) are linked by the bifunctional ligands, forming infinite (110) sheets. The cationic sheets are charge-balanced by inter-layer perchlorate ions. A free 1,5-bis-(pyridin-4-yl)pentane mol-ecule and an ethanol mol-ecule of crystallization are also found in the inter-sheet region. A number of O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds help to consolidate the layered structure.

AB - The title compound, poly[[di-aqua-bis-[1,5-bis-(pyridin-4-yl)pentane-κ(2) N:N']cadmium] bis-(perchlorate) 1,5-bis-(pyridin-4-yl)pentane ethanol mono-solvate], [Cd(C15H18N2)2(H2O)2](ClO4)2·C15H18N2·C2H6O, is a layered coordination polymer built up from highly squashed 4(4) nets in which the octa-hedral trans-CdO2N4 nodes (Cd site symmetry -1) are linked by the bifunctional ligands, forming infinite (110) sheets. The cationic sheets are charge-balanced by inter-layer perchlorate ions. A free 1,5-bis-(pyridin-4-yl)pentane mol-ecule and an ethanol mol-ecule of crystallization are also found in the inter-sheet region. A number of O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds help to consolidate the layered structure.

KW - Cadmium

KW - Flexible ligand

KW - Layered coordination polymer

KW - crystal structure

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JO - Acta Crystallographica Section E: Structure Reports Online

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ER -

Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis-(pyridin-4-yl)pentane linkers

Abstract

Bibliographical note

Keywords

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