Crystal structure of bis(thiourea-jS)bis(triphenyl-phosphane-κP)silver(I) nitrate

Sidra Nawaz, Muhammad Nawaz Tahir*, Muhammad Amir Nadeem, Bushra Mehmood, Saeed Ahmad, W. T A Harrison (Editor)

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)
9 Downloads (Pure)


In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the AgI atom is coordinated by two thiourea S atoms and two triphenylphosphane P atoms in a distorted tetrahedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°. The Ag - S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C - H⋯O, C - H⋯S, N - H⋯O and N - H⋯S hydrogen bonds, generating (101¯) sheets.

Original languageEnglish
Pages (from-to)220-222
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
Issue number2
Early online date28 Jan 2015
Publication statusPublished - 1 Feb 2015

Bibliographical note

The authors acknowledge the provision of funds for the purchase of a diffractometer and encouragement by Dr Muhammad Akram Chaudhary, Vice Chancellor, University of Sargodha, Pakistan.


  • Crystal structure
  • Hydrogen bonding
  • Silver(I) complex
  • Thiourea
  • Triphenyl-phosphane


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