Fosbergenone: 3-[2-(1,2,5,5-Tetramethyl-7-oxo-1,2,3,4,4a,5,6,7-octahydronaphthalen-1-yl)ethyl]-2,5-dihydrofuran-2-one

Joy Ebenezer Rajakulendran; Emmanuel T. Oluwabusola; Rainer Ebel; Marcel Jaspars

doi:10.3390/M1391

Fosbergenone: 3-[2-(1,2,5,5-Tetramethyl-7-oxo-1,2,3,4,4a,5,6,7-octahydronaphthalen-1-yl)ethyl]-2,5-dihydrofuran-2-one

Joy Ebenezer Rajakulendran^* (Corresponding Author), Emmanuel T. Oluwabusola, Rainer Ebel, Marcel Jaspars^* (Corresponding Author)

^*Corresponding author for this work

Eastern University, Sri Lanka

Research output: Contribution to journal › Comment/debate › peer-review

1 Citation (Scopus)

Abstract

A new ent-halimane diterpenoid, fosbergenone (1) was isolated from the foliar bud exudate of Gardenia fosbergii. The structure of 1 was elucidated based on spectroscopic data including IR, 1D and 2D NMR, as well as high-resolution mass spectrometry.

Original language	English
Article number	M1391
Number of pages	7
Journal	MolBank
Volume	2022
Issue number	2
Early online date	19 Jun 2022
DOIs	https://doi.org/10.3390/M1391 https://doi.org/10.3390/M1574
Publication status	Published - 19 Jun 2022

Bibliographical note

Funding: This research was funded by the Accelerating Higher Education Expansion and Development (AHEAD) operation Sri Lanka.

The authors gratefully acknowledge and appreciate the efforts of Loganayagam Romesh and Rasiah Rajakulendran in shipping the sample and obtaining the export permit, material transfer agreement and phytosanitary certificate of the plant resin. We extend our sincere gratitude to Suganthini Loganayagam and Dr Rukshani Rajakulendran for purchasing the plant resin for our research. The authors also acknowledge Seevaratnam Premkumar for providing photographs of the plant.

Correction: Rajakulendran et al. Fosbergenone: 3-[2-(1,2,5,5-Tetramethyl-7-oxo-1,2,3,4,4a,5,6,7-octahydronaphthalen-1-yl)ethyl]-2,5-dihydrofuran-2-one(Molbank (2022), 2022, (2), (M1391), 10.3390/M1391)

Data Availability Statement

Supplementary Materials: The following supporting information can be downloaded online. Figure S1: Annotated mass spectrum of compound 1; Figure S2: Annotated UV spectrum of compound 1;
Figure S3: IR spectrum of compound 1; Figure S4: Annotated 1H-NMR spectrum of compound 1 in CD3OD-d4 at 400 MHz; Figure S5: Annotated 13C-NMR spectrum of compound 1 in CD3OD-d4 at 100 MHz; Figure S6: HSQC spectrum of compound 1 in CD3OD-d4; Figure S7: COSY spectrum of compound 1 in CD3OD-d4; Figure S8: HMBC spectrum of compound 1 in CD3OD-d4: Figure S9: 2D NOESY spectrum of compound 1 in CD3OD-d4. Table S1. COSY and HMBC correlations of compound 1.

Keywords

2D NMR
diterpenoid
fosbergenone
Gardenia fosbergii
high-resolution mass spectrometry

Access to Document

10.3390/M1391Licence: CC BY
10.3390/M1574Licence: CC BY

Rajakulendran_etal_MB_Fosbergenone_VOR
© 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Final published version, 2.69 MBLicence: CC BY

Cite this

@article{70210a278098409289af357dad6181ec,

title = "Fosbergenone: 3-[2-(1,2,5,5-Tetramethyl-7-oxo-1,2,3,4,4a,5,6,7-octahydronaphthalen-1-yl)ethyl]-2,5-dihydrofuran-2-one",

abstract = "A new ent-halimane diterpenoid, fosbergenone (1) was isolated from the foliar bud exudate of Gardenia fosbergii. The structure of 1 was elucidated based on spectroscopic data including IR, 1D and 2D NMR, as well as high-resolution mass spectrometry.",

keywords = "2D NMR, diterpenoid, fosbergenone, Gardenia fosbergii, high-resolution mass spectrometry",

author = "Rajakulendran, {Joy Ebenezer} and Oluwabusola, {Emmanuel T.} and Rainer Ebel and Marcel Jaspars",

note = "Funding: This research was funded by the Accelerating Higher Education Expansion and Development (AHEAD) operation Sri Lanka. The authors gratefully acknowledge and appreciate the efforts of Loganayagam Romesh and Rasiah Rajakulendran in shipping the sample and obtaining the export permit, material transfer agreement and phytosanitary certificate of the plant resin. We extend our sincere gratitude to Suganthini Loganayagam and Dr Rukshani Rajakulendran for purchasing the plant resin for our research. The authors also acknowledge Seevaratnam Premkumar for providing photographs of the plant. Correction: Rajakulendran et al. Fosbergenone: 3-[2-(1,2,5,5-Tetramethyl-7-oxo-1,2,3,4,4a,5,6,7-octahydronaphthalen-1-yl)ethyl]-2,5-dihydrofuran-2-one(Molbank (2022), 2022, (2), (M1391), 10.3390/M1391)",

year = "2022",

month = jun,

day = "19",

doi = "10.3390/M1391",

language = "English",

volume = "2022",

journal = "MolBank",

issn = "1422-8599",

publisher = "MDPI AG",

number = "2",

}

TY - JOUR

T1 - Fosbergenone

T2 - 3-[2-(1,2,5,5-Tetramethyl-7-oxo-1,2,3,4,4a,5,6,7-octahydronaphthalen-1-yl)ethyl]-2,5-dihydrofuran-2-one

AU - Rajakulendran, Joy Ebenezer

AU - Oluwabusola, Emmanuel T.

AU - Ebel, Rainer

AU - Jaspars, Marcel

N1 - Funding: This research was funded by the Accelerating Higher Education Expansion and Development (AHEAD) operation Sri Lanka. The authors gratefully acknowledge and appreciate the efforts of Loganayagam Romesh and Rasiah Rajakulendran in shipping the sample and obtaining the export permit, material transfer agreement and phytosanitary certificate of the plant resin. We extend our sincere gratitude to Suganthini Loganayagam and Dr Rukshani Rajakulendran for purchasing the plant resin for our research. The authors also acknowledge Seevaratnam Premkumar for providing photographs of the plant. Correction: Rajakulendran et al. Fosbergenone: 3-[2-(1,2,5,5-Tetramethyl-7-oxo-1,2,3,4,4a,5,6,7-octahydronaphthalen-1-yl)ethyl]-2,5-dihydrofuran-2-one(Molbank (2022), 2022, (2), (M1391), 10.3390/M1391)

PY - 2022/6/19

Y1 - 2022/6/19

N2 - A new ent-halimane diterpenoid, fosbergenone (1) was isolated from the foliar bud exudate of Gardenia fosbergii. The structure of 1 was elucidated based on spectroscopic data including IR, 1D and 2D NMR, as well as high-resolution mass spectrometry.

AB - A new ent-halimane diterpenoid, fosbergenone (1) was isolated from the foliar bud exudate of Gardenia fosbergii. The structure of 1 was elucidated based on spectroscopic data including IR, 1D and 2D NMR, as well as high-resolution mass spectrometry.

KW - 2D NMR

KW - diterpenoid

KW - fosbergenone

KW - Gardenia fosbergii

KW - high-resolution mass spectrometry

UR - http://www.scopus.com/inward/record.url?scp=85132855272&partnerID=8YFLogxK

U2 - 10.3390/M1391

DO - 10.3390/M1391

M3 - Comment/debate

AN - SCOPUS:85132855272

SN - 1422-8599

VL - 2022

JO - MolBank

JF - MolBank

IS - 2

M1 - M1391

ER -

Fosbergenone: 3-[2-(1,2,5,5-Tetramethyl-7-oxo-1,2,3,4,4a,5,6,7-octahydronaphthalen-1-yl)ethyl]-2,5-dihydrofuran-2-one

Abstract

Bibliographical note

Data Availability Statement

Keywords

Access to Document

Other files and links

Fingerprint

Cite this