Fractional crystallization of garnet in alkali basalts at >1.8 GPa and implications for geochemical diversity of Large Igneous Provinces

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Abstract

A suite of lavas from northwest Mull, British Palaeocene Igneous Province, exhibit major and trace element characteristics that are best explained by very high pressure (>1.8 GPa) crystallization of an assemblage comprising aluminous clinopyroxene (Al-Cpx) plus garnet. The resulting series of consanguineous magmas are mildly Si-undersaturated. The trace element effects of this crystallizing assemblage are manifested in increasing light rare earth element (LREE) enrichment and heavy REE (HREE) depletion with decreasing whole-rock MgO, a predictable consequence of the bulk distribution coefficient (D) of this assemblage being > > 1 for HREE but
Original languageEnglish
Article number107397
JournalLithos
Volume460-461
Early online date19 Oct 2023
DOIs
Publication statusPublished - 1 Dec 2023

Bibliographical note

Acknowledgements
We thank Jussi Heinonen and an anonymous reviewer for a constructive and thoughtful criticism. We thank James Westland for pointing us at useful and interesting localities on the Isle of Mull. This study was part funded by a University of Aberdeen Elphinstone Scholarship to JHP.

Keywords

  • Garnet fractionation
  • Petrology
  • Pressure
  • Mull
  • Basalt
  • Petrogenesis

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