From Simple Electrolyte Solutions Through Polymer Electrolytes to Superionic Rubbers: Some Fundamental Considerations

C. Austen Angell; Corrie T. Imrie; Malcolm D. Ingram

From Simple Electrolyte Solutions Through Polymer Electrolytes to Superionic Rubbers: Some Fundamental Considerations

C. Austen Angell, Corrie T. Imrie, Malcolm D. Ingram^*

^*Corresponding author for this work

Arizona State University

Research output: Contribution to journal › Article › peer-review

71 Citations (Scopus)

Abstract

A general discussion is presented for the conductivity-viscosity and viscosity-temperature relationships in polymer electrolytes in the context of systematizing the efforts to obtain higher ionic conductivities at ambient temperatures. Topics discussed include: the Walden rule, glass-rubber and rubber-melt transitions, the strength-fragility concept, the Vogel-Fulcher-Tammann and Williams-Landel-Ferry equations, the chelation effect and the decoupling of ionic transport from the structural relaxation processes.

Original language	English
Pages (from-to)	9-15
Number of pages	7
Journal	Polymer International
Volume	47
Issue number	1
Publication status	Published - 1 Dec 1998

Keywords

Decoupling effects
Polymer electrolytes
Transport mechanisms

Cite this

@article{ca1a6a7d3de643a09f552ed7180a975c,

title = "From Simple Electrolyte Solutions Through Polymer Electrolytes to Superionic Rubbers: Some Fundamental Considerations",

abstract = "A general discussion is presented for the conductivity-viscosity and viscosity-temperature relationships in polymer electrolytes in the context of systematizing the efforts to obtain higher ionic conductivities at ambient temperatures. Topics discussed include: the Walden rule, glass-rubber and rubber-melt transitions, the strength-fragility concept, the Vogel-Fulcher-Tammann and Williams-Landel-Ferry equations, the chelation effect and the decoupling of ionic transport from the structural relaxation processes.",

keywords = "Decoupling effects, Polymer electrolytes, Transport mechanisms",

author = "Angell, {C. Austen} and Imrie, {Corrie T.} and Ingram, {Malcolm D.}",

year = "1998",

month = dec,

day = "1",

language = "English",

volume = "47",

pages = "9--15",

journal = "Polymer International",

issn = "0959-8103",

publisher = "John Wiley and Sons Ltd",

number = "1",

}

TY - JOUR

T1 - From Simple Electrolyte Solutions Through Polymer Electrolytes to Superionic Rubbers

T2 - Some Fundamental Considerations

AU - Angell, C. Austen

AU - Imrie, Corrie T.

AU - Ingram, Malcolm D.

PY - 1998/12/1

Y1 - 1998/12/1

N2 - A general discussion is presented for the conductivity-viscosity and viscosity-temperature relationships in polymer electrolytes in the context of systematizing the efforts to obtain higher ionic conductivities at ambient temperatures. Topics discussed include: the Walden rule, glass-rubber and rubber-melt transitions, the strength-fragility concept, the Vogel-Fulcher-Tammann and Williams-Landel-Ferry equations, the chelation effect and the decoupling of ionic transport from the structural relaxation processes.

AB - A general discussion is presented for the conductivity-viscosity and viscosity-temperature relationships in polymer electrolytes in the context of systematizing the efforts to obtain higher ionic conductivities at ambient temperatures. Topics discussed include: the Walden rule, glass-rubber and rubber-melt transitions, the strength-fragility concept, the Vogel-Fulcher-Tammann and Williams-Landel-Ferry equations, the chelation effect and the decoupling of ionic transport from the structural relaxation processes.

KW - Decoupling effects

KW - Polymer electrolytes

KW - Transport mechanisms

UR - http://www.scopus.com/inward/record.url?scp=0032154866&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0032154866

SN - 0959-8103

VL - 47

SP - 9

EP - 15

JO - Polymer International

JF - Polymer International

IS - 1

ER -

From Simple Electrolyte Solutions Through Polymer Electrolytes to Superionic Rubbers: Some Fundamental Considerations

Abstract

Keywords

Other files and links

Fingerprint

Cite this