@inproceedings{8c1b27b4177e422c871935737adb823c,
title = "Intrinsic dipole moments and electron transfer at MIEC-Gas Interfaces",
abstract = "The magnitude of the electrostatic potential at the surface of a mixed ionicelectronic conducting (MIEC) solid-oxide cell (SOC) electrode is dependent on the intrinsic dipole moment of adsorbed gas species. Using density functional theory, we have investigated the electrostatic nature of hydroxyl adsorbates and the kinetics of electron transfer in the water electrolysis reaction at the pristine ceria-gas interface. First principles data ware used in a generalised kinetic model to predict reaction kinetics near equilibrium and under an applied overpotential. The mechanistic understanding gained from this model is widely applicable to a range of MIEC systems and provides a basis upon which the operating conditions can be tailored.",
author = "Williams, {Nicholas J.} and Seymour, {Ieuan D.} and Leah, {Robert T.} and Subhasish Mukerjee and Mark Selby and Skinner, {Stephen J.}",
year = "2021",
doi = "10.1149/10301.0973ecst",
language = "English",
series = "ECS Transactions",
publisher = "IOP Publishing Ltd.",
number = "1",
pages = "973--979",
booktitle = "17th International Symposium on Solid Oxide Fuel Cells, SOFC 2021",
address = "United Kingdom",
edition = "1",
note = "17th International Symposium on Solid Oxide Fuel Cells, SOFC 2021 ; Conference date: 18-07-2021 Through 23-07-2021",
}