Abstract
Pd3P and PdP2 phases of ca. 4 nm were prepared on a TiO2 support by an impregnation route. Data from the hydrogenation of acetylene under both non-competitive and competitive conditions showed that PdP2/TiO2 exhibits enhanced selectivity and stability relative to Pd3P. Furthermore, the selectivity produced over PdP2 (84% ethylene selectivity @ 100% acetylene conversion) compares favorably with recently reported materials. XPS and CO-IR measurements reveal that the incorporation of P helps to break up contiguous Pd sites. This in turn is thought to affect the adsorption and desorption of reactants/products and thus improves selectivity. This work reveals that the incorporation of P into Pd materials could be regarded as a promising approach to develop new and improved Pd-based catalyst by creating a means to control the nature of the active sites.
Original language | English |
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Pages (from-to) | 406-414 |
Number of pages | 9 |
Journal | Journal of Catalysis |
Volume | 364 |
Early online date | 23 Jun 2018 |
DOIs | |
Publication status | Published - Aug 2018 |
Bibliographical note
This work was supported by the National Key Research and Development Program of China (2016YFB0301601), National Natural Science Foundation of China.Keywords
- palladium phosphide
- selective hydrogenation
- alkyne
- acetylene
- ethylene
- site-isolation