The synthesis, structure and some properties of the one-dimensional coordination polymer, [Pr2(pdc)3(Hpdc)]n•n(H3hp)•8n(H2O), (H2pdc = pyridine 2,6-dicarboxylic acid, C7H5NO4; 3hp = 3-hydroxypyridine, C5H5NO) are described. One of the Pr3+ ions is coordinated by two O,N,O-tridentate pdc2-ligands and one tridentate Hpdc- anion to generate a fairly regular PrO6N3 tri-capped trigonal prism, with the N atoms acting as the caps. The second Pr3+ ion is coordinated by one tridentate pdc2- dianion, four water molecules and two monodentate bridging pdc2- ligands to result in a PrO8N coordination polyhedron that approximates to a mono-capped square-anti-prism. The ligands bridge the metal-atom nodes into a chain, which extends in the  direction. The H3hp+ cation and uncoordinated water molecules occupy the inter-chain regions and an N-HLO and numerous O-HLO hydrogen bonds consolidate the structure. The H3hp+species appears to intercalate between pendant pdc rings to consolidate the polymeric structure. Crystal data:1 (C33H43N5O29Pr2), Mr = 1255.54, triclinic, P1(No. 2), Z = 2, a = 13.2567(1) Å, b = 13.6304(2) Å, c = 13.6409(2) Å,α = 89.695(1)°, β = 63.049(1)°, γ = 86.105(1)°, V = 2191.16(5) Å3, R(F) = 0.033, wR(F2) = 0.084.
- One-dimensional coordination polymer