Pretreatment of Miscanthus giganteus with Lime and Oxidants for Biofuels

Fuxin Yang; Zhongguo Liu; Waheed Afzal; Alexis T Bell; John M Prausnitz

doi:10.1021/ef502517d

Pretreatment of Miscanthus giganteus with Lime and Oxidants for Biofuels

Fuxin Yang, Zhongguo Liu, Waheed Afzal, Alexis T Bell, John M Prausnitz

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

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Abstract

To make biomass more accessible for enzymatic hydrolysis, lime pretreatment of Miscanthus giganteus with oxidants was explored from 100 to 150 °C. Composition data for the recovered solid were obtained to determine the effects of the reaction time, lime dosage, oxidant loading, and temperature on sugar production efficiency. Under selected conditions (0.2 g of lime/g of biomass, 200 psig O2, and 150 °C for 1 h), delignification was 64.7%. The pretreated biomass was then followed by enzymatic hydrolysis. The yield of cellulose in the recovered solid to glucose was 91.7% and hemicellulose to xylose was 67.3%, 7.1 and 18.2 times larger than those obtained from raw biomass, respectively. Pretreatment with oxidants substantially raised delignification of raw M. giganteus, thereby enhancing enzymatic hydrolysis to sugars, while results were not improved when pretreatment included ammonium molybdate.

Original language	English
Pages (from-to)	1743-1750
Number of pages	8
Journal	Energy & Fuels
Volume	29
Issue number	3
Early online date	10 Feb 2015
DOIs	https://doi.org/10.1021/ef502517d
Publication status	Published - 2015

Bibliographical note

ACKNOWLEDEGMENTS
The authors are grateful to the Energy Biosciences Institute, University of California, Berkeley, Berkeley, CA, for financial support, Dr. Stefan R. Bauer, Valerie D. Mitchell, and Ana Belen Ibanez Zamora for technical assistance, and Jason Cai for fruitful discussions. The authors thank the China Scholarship Council for financial assistance to Fuxin Yang during his stay at University of California, Berkeley.

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This document is the Accepted Manuscript version of a Published Work that appeared in final form in Energy & Fuels copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see doi: 10.1021/ef502517d
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Cite this

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title = "Pretreatment of Miscanthus giganteus with Lime and Oxidants for Biofuels",

abstract = "To make biomass more accessible for enzymatic hydrolysis, lime pretreatment of Miscanthus giganteus with oxidants was explored from 100 to 150 °C. Composition data for the recovered solid were obtained to determine the effects of the reaction time, lime dosage, oxidant loading, and temperature on sugar production efficiency. Under selected conditions (0.2 g of lime/g of biomass, 200 psig O2, and 150 °C for 1 h), delignification was 64.7%. The pretreated biomass was then followed by enzymatic hydrolysis. The yield of cellulose in the recovered solid to glucose was 91.7% and hemicellulose to xylose was 67.3%, 7.1 and 18.2 times larger than those obtained from raw biomass, respectively. Pretreatment with oxidants substantially raised delignification of raw M. giganteus, thereby enhancing enzymatic hydrolysis to sugars, while results were not improved when pretreatment included ammonium molybdate.",

author = "Fuxin Yang and Zhongguo Liu and Waheed Afzal and Bell, {Alexis T} and Prausnitz, {John M}",

note = "ACKNOWLEDEGMENTS The authors are grateful to the Energy Biosciences Institute, University of California, Berkeley, Berkeley, CA, for financial support, Dr. Stefan R. Bauer, Valerie D. Mitchell, and Ana Belen Ibanez Zamora for technical assistance, and Jason Cai for fruitful discussions. The authors thank the China Scholarship Council for financial assistance to Fuxin Yang during his stay at University of California, Berkeley.",

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AU - Yang, Fuxin

AU - Liu, Zhongguo

AU - Afzal, Waheed

AU - Bell, Alexis T

AU - Prausnitz, John M

N1 - ACKNOWLEDEGMENTS The authors are grateful to the Energy Biosciences Institute, University of California, Berkeley, Berkeley, CA, for financial support, Dr. Stefan R. Bauer, Valerie D. Mitchell, and Ana Belen Ibanez Zamora for technical assistance, and Jason Cai for fruitful discussions. The authors thank the China Scholarship Council for financial assistance to Fuxin Yang during his stay at University of California, Berkeley.

PY - 2015

Y1 - 2015

N2 - To make biomass more accessible for enzymatic hydrolysis, lime pretreatment of Miscanthus giganteus with oxidants was explored from 100 to 150 °C. Composition data for the recovered solid were obtained to determine the effects of the reaction time, lime dosage, oxidant loading, and temperature on sugar production efficiency. Under selected conditions (0.2 g of lime/g of biomass, 200 psig O2, and 150 °C for 1 h), delignification was 64.7%. The pretreated biomass was then followed by enzymatic hydrolysis. The yield of cellulose in the recovered solid to glucose was 91.7% and hemicellulose to xylose was 67.3%, 7.1 and 18.2 times larger than those obtained from raw biomass, respectively. Pretreatment with oxidants substantially raised delignification of raw M. giganteus, thereby enhancing enzymatic hydrolysis to sugars, while results were not improved when pretreatment included ammonium molybdate.

AB - To make biomass more accessible for enzymatic hydrolysis, lime pretreatment of Miscanthus giganteus with oxidants was explored from 100 to 150 °C. Composition data for the recovered solid were obtained to determine the effects of the reaction time, lime dosage, oxidant loading, and temperature on sugar production efficiency. Under selected conditions (0.2 g of lime/g of biomass, 200 psig O2, and 150 °C for 1 h), delignification was 64.7%. The pretreated biomass was then followed by enzymatic hydrolysis. The yield of cellulose in the recovered solid to glucose was 91.7% and hemicellulose to xylose was 67.3%, 7.1 and 18.2 times larger than those obtained from raw biomass, respectively. Pretreatment with oxidants substantially raised delignification of raw M. giganteus, thereby enhancing enzymatic hydrolysis to sugars, while results were not improved when pretreatment included ammonium molybdate.

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JO - Energy & Fuels

JF - Energy & Fuels

IS - 3

ER -

Pretreatment of Miscanthus giganteus with Lime and Oxidants for Biofuels

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