Selectivity of reaction pathways for green diesel production towards biojet fuel applications

Zeni Rahmawati, Liangga Santoso, Alan McCue, Nor Laili Azua Jamari, Sri Yayu Ninglasari, Triyanda Gunawan, Hamzah Fansuri

Research output: Contribution to journalReview articlepeer-review

1 Citation (Scopus)

Abstract

Green diesel is the second generation biofuel with the same structure as fossil fuels (alkanes), allowing this biofuel to provide excellent fuel properties over biodiesel such as higher energy content and lower hazardous gas emission. Generally, green diesel can be produced through the deoxygenation/hydrogenation of natural oil and/or its derivatives at 200-400 °C and 1-10 MPa over supported metal catalysts. This process comprises of three reaction pathways: hydrodeoxygenation, decarboxylation, and decarbonylation. The extent to which these three different pathways are involved is strongly influenced by the catalyst, pressure, and temperature. Subsequently, the determination of catalyst and reaction condition plays a significant role owing to the feasibility of the process and the economic point of view. This article emphasizes the reaction pathway of green diesel production as well as the parameters influencing the predominant reaction route.

Original languageEnglish
Pages (from-to)13698-13714
Number of pages17
JournalRSC Advances
Volume13
Issue number20
Early online date4 May 2023
DOIs
Publication statusE-pub ahead of print - 4 May 2023

Bibliographical note

Funding Information:
The authors thank the Ministry of Education, Culture, Research, and Technology Republik Indonesia for the research grant through the Penelitian Dasar Kompetitif Nasional scheme under main contract No. 084/E5/PG.02.00.PT/2022, and Researcher's Contract No. 1371/PKS/ITS/2022.

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