Semiconductor Oxide Photocatalysis for Organic Synthesis

N. Grant; John Mervyn David Storey; Russell Francis Howe

Semiconductor Oxide Photocatalysis for Organic Synthesis

N. Grant, John Mervyn David Storey, Russell Francis Howe

Research output: Contribution to journal › Article › peer-review

Abstract

The creation and reactivity of benzyl radicals produced by photooxidation of benzyltrimethylsilanes at the surface of TiO2 is described. Kinetic data have been obtained and the effects of the nature and position of substitutions on the benzylsilane ring have been investigated. In-situ EPR spectroscopy has been used to investigate the mechanism of the reaction.

Original language	English
Pages (from-to)	445-448
Number of pages	3
Journal	Studies in Surface Science and Catalysis
Volume	172
Publication status	Published - Aug 2007

Cite this

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title = "Semiconductor Oxide Photocatalysis for Organic Synthesis",

abstract = "The creation and reactivity of benzyl radicals produced by photooxidation of benzyltrimethylsilanes at the surface of TiO2 is described. Kinetic data have been obtained and the effects of the nature and position of substitutions on the benzylsilane ring have been investigated. In-situ EPR spectroscopy has been used to investigate the mechanism of the reaction.",

author = "N. Grant and Storey, {John Mervyn David} and Howe, {Russell Francis}",

year = "2007",

month = aug,

language = "English",

volume = "172",

pages = "445--448",

journal = "Studies in Surface Science and Catalysis",

issn = "0167-2991",

publisher = "Elsevier BV",

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TY - JOUR

T1 - Semiconductor Oxide Photocatalysis for Organic Synthesis

AU - Grant, N.

AU - Storey, John Mervyn David

AU - Howe, Russell Francis

PY - 2007/8

Y1 - 2007/8

N2 - The creation and reactivity of benzyl radicals produced by photooxidation of benzyltrimethylsilanes at the surface of TiO2 is described. Kinetic data have been obtained and the effects of the nature and position of substitutions on the benzylsilane ring have been investigated. In-situ EPR spectroscopy has been used to investigate the mechanism of the reaction.

AB - The creation and reactivity of benzyl radicals produced by photooxidation of benzyltrimethylsilanes at the surface of TiO2 is described. Kinetic data have been obtained and the effects of the nature and position of substitutions on the benzylsilane ring have been investigated. In-situ EPR spectroscopy has been used to investigate the mechanism of the reaction.

M3 - Article

SN - 0167-2991

VL - 172

SP - 445

EP - 448

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

ER -

Semiconductor Oxide Photocatalysis for Organic Synthesis

Abstract

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