Steric variations between the synthesis of a stable chiral C-2-symmetric diimidazolidinylidene and an electron-rich tetraazafulvalene

C  Marshall; M F  Ward; J M S  Skakle

doi:10.1055/s-2006-926361

Steric variations between the synthesis of a stable chiral C-2-symmetric diimidazolidinylidene and an electron-rich tetraazafulvalene

C Marshall, M F Ward, J M S Skakle

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

C-2-Symmetric electron-rich olefin dimers and imidazolidinylidene ligands with a 2,2-dimethyl-1,3-dioxolane backbone were synthesised and characterised. The steric protection of the carbene dictates which product is obtained.

Original language	English
Pages (from-to)	1040-1044
Number of pages	5
Journal	Synthesis
Volume	6
DOIs	https://doi.org/10.1055/s-2006-926361
Publication status	Published - 2006

Keywords

electron-rich olefin dimer
imidazolidinylidene
chiral
C-2-symmetric
heterocyclic carbene ligands
ruthenium catalysts
olefin metathesis
metal-complexes
derivatives
palladium

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title = "Steric variations between the synthesis of a stable chiral C-2-symmetric diimidazolidinylidene and an electron-rich tetraazafulvalene",

abstract = "C-2-Symmetric electron-rich olefin dimers and imidazolidinylidene ligands with a 2,2-dimethyl-1,3-dioxolane backbone were synthesised and characterised. The steric protection of the carbene dictates which product is obtained.",

keywords = "electron-rich olefin dimer, imidazolidinylidene, chiral, C-2-symmetric, heterocyclic carbene ligands, ruthenium catalysts, olefin metathesis, metal-complexes, derivatives, palladium",

author = "C Marshall and Ward, {M F} and Skakle, {J M S}",

year = "2006",

doi = "10.1055/s-2006-926361",

language = "English",

volume = "6",

pages = "1040--1044",

journal = "Synthesis",

issn = "1437-210X",

publisher = "GEORG THIEME VERLAG KG",

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T1 - Steric variations between the synthesis of a stable chiral C-2-symmetric diimidazolidinylidene and an electron-rich tetraazafulvalene

AU - Marshall, C

AU - Ward, M F

AU - Skakle, J M S

PY - 2006

Y1 - 2006

N2 - C-2-Symmetric electron-rich olefin dimers and imidazolidinylidene ligands with a 2,2-dimethyl-1,3-dioxolane backbone were synthesised and characterised. The steric protection of the carbene dictates which product is obtained.

AB - C-2-Symmetric electron-rich olefin dimers and imidazolidinylidene ligands with a 2,2-dimethyl-1,3-dioxolane backbone were synthesised and characterised. The steric protection of the carbene dictates which product is obtained.

KW - electron-rich olefin dimer

KW - imidazolidinylidene

KW - chiral

KW - C-2-symmetric

KW - heterocyclic carbene ligands

KW - ruthenium catalysts

KW - olefin metathesis

KW - metal-complexes

KW - derivatives

KW - palladium

U2 - 10.1055/s-2006-926361

DO - 10.1055/s-2006-926361

M3 - Article

SN - 1437-210X

VL - 6

SP - 1040

EP - 1044

JO - Synthesis

JF - Synthesis

ER -

Steric variations between the synthesis of a stable chiral C-2-symmetric diimidazolidinylidene and an electron-rich tetraazafulvalene

Abstract

Keywords

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