The solution-mediated syntheses and single crystal structures of the new open-framework phases (CH3NH3)(3). Zn4O(AsO4)(3) and (CH3NH3)(3). Zn4O(PO4)(3) are reported. These compounds are built up from vertex-sharing three-dimensional "OZn4" + ZnO4 + AsO4/PO4 tetrahedral frameworks encapsulating methylammonium cations in three-dimensional channel systems. These phases are closely related to the zeolite-like M3Zn4O(XO4)(3). nH(2)O family of phases.
|Number of pages||6|
|Journal||Journal of Materials Chemistry|
|Publication status||Published - 1999|
- ROOM-TEMPERATURE SYNTHESIS