Synthesis and characterisation of polymeric manganese and zinc 5-hydroxyisophthalates

Michael John Plater; M. R. S. J. Foreman; Robert Alan Howie; Janet Mabel Scott Skakle; S. A. McWilliam; E. Coronado; C. J. Gomez-Garcia

doi:10.1016/S0277-5387(01)00804-X

Synthesis and characterisation of polymeric manganese and zinc 5-hydroxyisophthalates

Michael John Plater, M. R. S. J. Foreman, Robert Alan Howie, Janet Mabel Scott Skakle, S. A. McWilliam, E. Coronado, C. J. Gomez-Garcia

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43 Citations (Web of Science)

Abstract

The crystallisation of 5-hydroxyisophthalic acid with divalent Mn or with Mn or Zn and either 2,2-bipyridine (2,2-bipy) or pyridine-2-(1H-pyrazol-3-yl) gave solids of composition [Mn(C8H4O5)(H2O)(3)]. 2H(2)O (1), [Mn(C8H4O5)(2,2 ' -bipy)].H2O (2), [Mn-2(C8H4O5)(2)(C8H7N3)(2)].H2O (3) and [Zn(C8H4O5)(2,2 ' -bipy)] (4). Each compound has 1D co-ordinative chains that are connected by hydrogen bonds. Compounds 2-4 contain M2C2O4 rings with pseudo-chair geometries. The Mn atoms in 2 are coupled antiferromagnetically. (C) 2001 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	2293-2303
Number of pages	10
Journal	Polyhedron
Volume	20
DOIs	https://doi.org/10.1016/S0277-5387(01)00804-X
Publication status	Published - 2001

Keywords

manganese
hydrothermal
co-ordination polymer
X-RAY STRUCTURE
MAGNETIC-PROPERTIES
CRYSTAL-STRUCTURE
COMPLEXES
CHAIN
OXIDATION
BEHAVIOR
BRIDGES

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@article{fe7144ed5b3e474e87f606b5b245b6f0,

title = "Synthesis and characterisation of polymeric manganese and zinc 5-hydroxyisophthalates",

abstract = "The crystallisation of 5-hydroxyisophthalic acid with divalent Mn or with Mn or Zn and either 2,2-bipyridine (2,2-bipy) or pyridine-2-(1H-pyrazol-3-yl) gave solids of composition [Mn(C8H4O5)(H2O)(3)]. 2H(2)O (1), [Mn(C8H4O5)(2,2 ' -bipy)].H2O (2), [Mn-2(C8H4O5)(2)(C8H7N3)(2)].H2O (3) and [Zn(C8H4O5)(2,2 ' -bipy)] (4). Each compound has 1D co-ordinative chains that are connected by hydrogen bonds. Compounds 2-4 contain M2C2O4 rings with pseudo-chair geometries. The Mn atoms in 2 are coupled antiferromagnetically. (C) 2001 Elsevier Science Ltd. All rights reserved.",

keywords = "manganese, hydrothermal, co-ordination polymer, X-RAY STRUCTURE, MAGNETIC-PROPERTIES, CRYSTAL-STRUCTURE, COMPLEXES, CHAIN, OXIDATION, BEHAVIOR, BRIDGES",

author = "Plater, {Michael John} and Foreman, {M. R. S. J.} and Howie, {Robert Alan} and Skakle, {Janet Mabel Scott} and McWilliam, {S. A.} and E. Coronado and Gomez-Garcia, {C. J.}",

year = "2001",

doi = "10.1016/S0277-5387(01)00804-X",

language = "English",

volume = "20",

pages = "2293--2303",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

}

TY - JOUR

T1 - Synthesis and characterisation of polymeric manganese and zinc 5-hydroxyisophthalates

AU - Plater, Michael John

AU - Foreman, M. R. S. J.

AU - Howie, Robert Alan

AU - Skakle, Janet Mabel Scott

AU - McWilliam, S. A.

AU - Coronado, E.

AU - Gomez-Garcia, C. J.

PY - 2001

Y1 - 2001

N2 - The crystallisation of 5-hydroxyisophthalic acid with divalent Mn or with Mn or Zn and either 2,2-bipyridine (2,2-bipy) or pyridine-2-(1H-pyrazol-3-yl) gave solids of composition [Mn(C8H4O5)(H2O)(3)]. 2H(2)O (1), [Mn(C8H4O5)(2,2 ' -bipy)].H2O (2), [Mn-2(C8H4O5)(2)(C8H7N3)(2)].H2O (3) and [Zn(C8H4O5)(2,2 ' -bipy)] (4). Each compound has 1D co-ordinative chains that are connected by hydrogen bonds. Compounds 2-4 contain M2C2O4 rings with pseudo-chair geometries. The Mn atoms in 2 are coupled antiferromagnetically. (C) 2001 Elsevier Science Ltd. All rights reserved.

AB - The crystallisation of 5-hydroxyisophthalic acid with divalent Mn or with Mn or Zn and either 2,2-bipyridine (2,2-bipy) or pyridine-2-(1H-pyrazol-3-yl) gave solids of composition [Mn(C8H4O5)(H2O)(3)]. 2H(2)O (1), [Mn(C8H4O5)(2,2 ' -bipy)].H2O (2), [Mn-2(C8H4O5)(2)(C8H7N3)(2)].H2O (3) and [Zn(C8H4O5)(2,2 ' -bipy)] (4). Each compound has 1D co-ordinative chains that are connected by hydrogen bonds. Compounds 2-4 contain M2C2O4 rings with pseudo-chair geometries. The Mn atoms in 2 are coupled antiferromagnetically. (C) 2001 Elsevier Science Ltd. All rights reserved.

KW - manganese

KW - hydrothermal

KW - co-ordination polymer

KW - X-RAY STRUCTURE

KW - MAGNETIC-PROPERTIES

KW - CRYSTAL-STRUCTURE

KW - COMPLEXES

KW - CHAIN

KW - OXIDATION

KW - BEHAVIOR

KW - BRIDGES

U2 - 10.1016/S0277-5387(01)00804-X

DO - 10.1016/S0277-5387(01)00804-X

M3 - Article

SN - 0277-5387

VL - 20

SP - 2293

EP - 2303

JO - Polyhedron

JF - Polyhedron

ER -

Synthesis and characterisation of polymeric manganese and zinc 5-hydroxyisophthalates

Abstract

Keywords

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