Synthesis and structure of C2-symmetric N-heterocyclic carbene complexes of palladium

Colin Marshall; M. F. Ward; William Thomas Alexander Harrison

doi:10.1016/j.tetlet.2004.05.085

Synthesis and structure of C₂-symmetric N-heterocyclic carbene complexes of palladium

Colin Marshall, M. F. Ward, William Thomas Alexander Harrison

Chemistry

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

The first 9- and 11-membered cis and trans C-2-symmetric benzimidazol-2-ylidene palladium(11) complexes based on a trans-2,2-dimethyl-1,3-dioxalane backbone were synthesised and the configuration of the complexes was elucidated via NMR and X-ray crystallography. (C) 2004 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	5703-5706
Number of pages	3
Journal	Tetrahedron Letters
Volume	45
DOIs	https://doi.org/10.1016/j.tetlet.2004.05.085
Publication status	Published - 2004

Keywords

C-2-symmetric
carbene
benzimidazol-2-ylidene palladium(II) complexes
OLEFIN METATHESIS
RUTHENIUM CATALYSTS
METAL-COMPLEXES
LIGANDS

Access to Document

10.1016/j.tetlet.2004.05.085

Cite this

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title = "Synthesis and structure of C2-symmetric N-heterocyclic carbene complexes of palladium",

abstract = "The first 9- and 11-membered cis and trans C-2-symmetric benzimidazol-2-ylidene palladium(11) complexes based on a trans-2,2-dimethyl-1,3-dioxalane backbone were synthesised and the configuration of the complexes was elucidated via NMR and X-ray crystallography. (C) 2004 Elsevier Ltd. All rights reserved.",

keywords = "C-2-symmetric, carbene, benzimidazol-2-ylidene palladium(II) complexes, OLEFIN METATHESIS, RUTHENIUM CATALYSTS, METAL-COMPLEXES, LIGANDS",

author = "Colin Marshall and Ward, {M. F.} and Harrison, {William Thomas Alexander}",

year = "2004",

doi = "10.1016/j.tetlet.2004.05.085",

language = "English",

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journal = "Tetrahedron Letters",

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AU - Marshall, Colin

AU - Ward, M. F.

AU - Harrison, William Thomas Alexander

PY - 2004

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N2 - The first 9- and 11-membered cis and trans C-2-symmetric benzimidazol-2-ylidene palladium(11) complexes based on a trans-2,2-dimethyl-1,3-dioxalane backbone were synthesised and the configuration of the complexes was elucidated via NMR and X-ray crystallography. (C) 2004 Elsevier Ltd. All rights reserved.

AB - The first 9- and 11-membered cis and trans C-2-symmetric benzimidazol-2-ylidene palladium(11) complexes based on a trans-2,2-dimethyl-1,3-dioxalane backbone were synthesised and the configuration of the complexes was elucidated via NMR and X-ray crystallography. (C) 2004 Elsevier Ltd. All rights reserved.

KW - C-2-symmetric

KW - carbene

KW - benzimidazol-2-ylidene palladium(II) complexes

KW - OLEFIN METATHESIS

KW - RUTHENIUM CATALYSTS

KW - METAL-COMPLEXES

KW - LIGANDS

U2 - 10.1016/j.tetlet.2004.05.085

DO - 10.1016/j.tetlet.2004.05.085

M3 - Article

SN - 0040-4039

VL - 45

SP - 5703

EP - 5706

JO - Tetrahedron Letters

JF - Tetrahedron Letters

ER -