Thallium titanium phosphate, Tl3Ti3O(PO4)(3)(P2O7)

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The title compound, trithallium trititanium oxide tris(phosphate) diphosphate, consists of a three-dimensional network of vertex-sharing TiO6, PO4 and P2O7 groups [d(av)(Ti-O) = 1.940(3) and d(av)(P-O) = 1.536(4)Angstrom]. Extra-framework Tl+ cations [d(av)(Tl-O) = 3.090(7)Angstrom] complete the structure, which is isostructural with M3Ti3O(PO4)(3)(P2O7) (M = K, Rb).

Original languageEnglish
Pages (from-to)1200-1203
Number of pages4
JournalActa Crystallographica Section C, Crystal Structure Communications
Publication statusPublished - 1999


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