The consistent hexameric paddle-wheel crystallisation motif of a family of 2,4-bis(n-alkylamino)nitrobenzenes: Alkyl = pentyl, hexyl, heptyl and octyl

M. John Plater; William T.A. Harrison; Laura M. Machado De Los Toyos; Lewis Hendry

doi:10.3184/174751917X14902201357356

The consistent hexameric paddle-wheel crystallisation motif of a family of 2,4-bis(n-alkylamino)nitrobenzenes: Alkyl = pentyl, hexyl, heptyl and octyl

M. John Plater^*, William T.A. Harrison, Laura M. Machado De Los Toyos, Lewis Hendry

^*Corresponding author for this work

Chemistry

University of Aberdeen

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

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Abstract

Three examples of 2,4-bis(n-alkylamino)nitrobenzenes have been crystallised (alkyl = pentyl, hexyl and heptyl) and the single crystal structures were determined. The three structures are similar and adopt a cyclic hydrogen bonded hexameric motif. n-Octyl alkyl chains prevented a crystal structure determination owing to disorder.

Original language	English
Pages (from-to)	235-238
Number of pages	4
Journal	Journal of Chemical Research
Volume	41
Issue number	4
Early online date	28 Mar 2017
DOIs	https://doi.org/10.3184/174751917X14902201357356
Publication status	Published - 1 Apr 2017

Bibliographical note

We thank the EPSRC National Mass Spectrometry Service (University of Swansea) for the mass spectrometry data and the EPSRC National Crystallography Service (University of Southampton) for the X-ray intensity data collections.

Keywords

2,4-bis(alkylamino)nitrobenzenes
Crystallisation
Hexameric
Hydrogen bond
Porous
Supramolecular

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Accepted Manuscript
This is an Accepted Manuscript of an article published by Science Reviews 2000 Ltd in Journal of Chemical Research on 28/03/2017, available online: https://doi.org/10.3184/174751917X14902201357356
Accepted author manuscript, 612 KBLicence: Unspecified

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The consistent hexameric paddle-wheel crystallisation motif of a family of 2,4-bis(n-alkylamino)nitrobenzenes: Alkyl = pentyl, hexyl, heptyl and octyl. / Plater, M. John ; Harrison, William T.A.; Machado De Los Toyos, Laura M. et al.
In: Journal of Chemical Research, Vol. 41, No. 4, 01.04.2017, p. 235-238.

Research output: Contribution to journal › Article › peer-review

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abstract = "Three examples of 2,4-bis(n-alkylamino)nitrobenzenes have been crystallised (alkyl = pentyl, hexyl and heptyl) and the single crystal structures were determined. The three structures are similar and adopt a cyclic hydrogen bonded hexameric motif. n-Octyl alkyl chains prevented a crystal structure determination owing to disorder.",

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The consistent hexameric paddle-wheel crystallisation motif of a family of 2,4-bis(n-alkylamino)nitrobenzenes: Alkyl = pentyl, hexyl, heptyl and octyl

Abstract

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Keywords

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