TY - JOUR
T1 - Three ethyl 5-amino-1-aryl-1H-imidazole-4-carboxylates
T2 - Hydrogen-bonded supramolecular structures in one, two and three dimensions
AU - Costa, M. S.
AU - Boechat, N.
AU - Wardell, S. M. S. V.
AU - Ferreira, V. F.
AU - Low, John N
AU - Glidewell, C.
PY - 2007/1
Y1 - 2007/1
N2 - The molecules of ethyl 5-amino-1-(4-cyanophenyl)-1H-imidazole-4-carboxylate, C13H12N4O2, are linked into a chain of alternating R-2(2)(10) and R-4(4)(34) rings by a combination of N-H center dot center dot center dot N and C-H center dot center dot center dot N hydrogen bonds. In ethyl 5-amino-1-(4-chlorophenyl)-1H-imidazole-4-carboxylate, C12H12ClN3O2, where the ethyl group is disordered over two sets of sites, a combination of N-H center dot center dot center dot O, N-H center dot center dot center dot N, C-H center dot center dot center dot N and C-H center dot center dot center dot pi(arene) hydrogen bonds links the molecules into complex sheets. Two intermolecular hydrogen bonds, one each of N-H center dot center dot center dot N and C-H center dot center dot center dot O types, link the molecules of ethyl 5-amino-1-(2,6-difluorophenyl)-1H-imidazole-4-carboxylate, C12H11F2N3O2, into a continuous three-dimensional framework structure.
AB - The molecules of ethyl 5-amino-1-(4-cyanophenyl)-1H-imidazole-4-carboxylate, C13H12N4O2, are linked into a chain of alternating R-2(2)(10) and R-4(4)(34) rings by a combination of N-H center dot center dot center dot N and C-H center dot center dot center dot N hydrogen bonds. In ethyl 5-amino-1-(4-chlorophenyl)-1H-imidazole-4-carboxylate, C12H12ClN3O2, where the ethyl group is disordered over two sets of sites, a combination of N-H center dot center dot center dot O, N-H center dot center dot center dot N, C-H center dot center dot center dot N and C-H center dot center dot center dot pi(arene) hydrogen bonds links the molecules into complex sheets. Two intermolecular hydrogen bonds, one each of N-H center dot center dot center dot N and C-H center dot center dot center dot O types, link the molecules of ethyl 5-amino-1-(2,6-difluorophenyl)-1H-imidazole-4-carboxylate, C12H11F2N3O2, into a continuous three-dimensional framework structure.
KW - derivatives
KW - agents
U2 - 10.1107/S0108270106048402
DO - 10.1107/S0108270106048402
M3 - Article
SN - 0108-2701
VL - 63
SP - o33-o37
JO - Acta Crystallographica Section C, Crystal Structure Communications
JF - Acta Crystallographica Section C, Crystal Structure Communications
IS - 1
ER -