Volumetric Properties of Furan and 2‑5-Dimethylfuran in Different Industrial Solvents at Temperatures from 278 to 343 K

Mohsin Raza; Alain Valtz; Christophe Coquelet; Paul Hallett; Waheed Afzal

doi:10.1021/acs.jced.0c01060

Volumetric Properties of Furan and 2‑5-Dimethylfuran in Different Industrial Solvents at Temperatures from 278 to 343 K

Mohsin Raza, Alain Valtz, Christophe Coquelet, Paul Hallett, Waheed Afzal^* (Corresponding Author)

^*Corresponding author for this work

CTP-Centre of Thermodynamics of Processes, MINES ParisTech PSL University

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

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Abstract

Density and speed of sound have been measured for pure components such as furan, 2-5-dimethylfuran (DMF), nmethyldiethanolamine (MDEA), diethylene glycol (DEG), tri ethylene glycol (TEG), and dimethylacetamide (DMA) using an Anton Paar (DSA-5000) vibrating U-tube densitometer in the temperature range of 278.15 to 343.15 K and ambient pressure (100 kPa). Density and speed of sound have been measured for furan + MDEA, furan + DEG, furan + TEG, and furan + DMA in the temperature range of 278.15 to 303.15 K, whereas for DMF +DMA, the temperature range is 283.15 to 343.15 K. Excess molar volume has been calculated for all binary systems. The Redlich−Kister model is used to correlate the experimental data. In order to identify the impact of molecular interactions participating significantly in the excess molar volume, the prigogine−Flory−Patterson model is selected to correlate and predict the deviations for excess molar volumes of the binary mixtures.

Original language	English
Pages (from-to)	2666-2680
Number of pages	15
Journal	Journal of Chemical and Engineering Data
Volume	66
Issue number	7
Early online date	18 Jun 2021
DOIs	https://doi.org/10.1021/acs.jced.0c01060
Publication status	Published - 8 Jul 2021

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title = "Volumetric Properties of Furan and 2‑5-Dimethylfuran in Different Industrial Solvents at Temperatures from 278 to 343 K",

abstract = "Density and speed of sound have been measured for pure components such as furan, 2-5-dimethylfuran (DMF), nmethyldiethanolamine (MDEA), diethylene glycol (DEG), tri ethylene glycol (TEG), and dimethylacetamide (DMA) using an Anton Paar (DSA-5000) vibrating U-tube densitometer in the temperature range of 278.15 to 343.15 K and ambient pressure (100 kPa). Density and speed of sound have been measured for furan + MDEA, furan + DEG, furan + TEG, and furan + DMA in the temperature range of 278.15 to 303.15 K, whereas for DMF +DMA, the temperature range is 283.15 to 343.15 K. Excess molar volume has been calculated for all binary systems. The Redlich−Kister model is used to correlate the experimental data. In order to identify the impact of molecular interactions participating significantly in the excess molar volume, the prigogine−Flory−Patterson model is selected to correlate and predict the deviations for excess molar volumes of the binary mixtures.",

author = "Mohsin Raza and Alain Valtz and Christophe Coquelet and Paul Hallett and Waheed Afzal",

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T1 - Volumetric Properties of Furan and 2‑5-Dimethylfuran in Different Industrial Solvents at Temperatures from 278 to 343 K

AU - Raza, Mohsin

AU - Valtz, Alain

AU - Coquelet, Christophe

AU - Hallett, Paul

AU - Afzal, Waheed

PY - 2021/7/8

Y1 - 2021/7/8

N2 - Density and speed of sound have been measured for pure components such as furan, 2-5-dimethylfuran (DMF), nmethyldiethanolamine (MDEA), diethylene glycol (DEG), tri ethylene glycol (TEG), and dimethylacetamide (DMA) using an Anton Paar (DSA-5000) vibrating U-tube densitometer in the temperature range of 278.15 to 343.15 K and ambient pressure (100 kPa). Density and speed of sound have been measured for furan + MDEA, furan + DEG, furan + TEG, and furan + DMA in the temperature range of 278.15 to 303.15 K, whereas for DMF +DMA, the temperature range is 283.15 to 343.15 K. Excess molar volume has been calculated for all binary systems. The Redlich−Kister model is used to correlate the experimental data. In order to identify the impact of molecular interactions participating significantly in the excess molar volume, the prigogine−Flory−Patterson model is selected to correlate and predict the deviations for excess molar volumes of the binary mixtures.

AB - Density and speed of sound have been measured for pure components such as furan, 2-5-dimethylfuran (DMF), nmethyldiethanolamine (MDEA), diethylene glycol (DEG), tri ethylene glycol (TEG), and dimethylacetamide (DMA) using an Anton Paar (DSA-5000) vibrating U-tube densitometer in the temperature range of 278.15 to 343.15 K and ambient pressure (100 kPa). Density and speed of sound have been measured for furan + MDEA, furan + DEG, furan + TEG, and furan + DMA in the temperature range of 278.15 to 303.15 K, whereas for DMF +DMA, the temperature range is 283.15 to 343.15 K. Excess molar volume has been calculated for all binary systems. The Redlich−Kister model is used to correlate the experimental data. In order to identify the impact of molecular interactions participating significantly in the excess molar volume, the prigogine−Flory−Patterson model is selected to correlate and predict the deviations for excess molar volumes of the binary mixtures.

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DO - 10.1021/acs.jced.0c01060

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VL - 66

SP - 2666

EP - 2680

JO - Journal of Chemical and Engineering Data

JF - Journal of Chemical and Engineering Data

IS - 7

ER -

Volumetric Properties of Furan and 2‑5-Dimethylfuran in Different Industrial Solvents at Temperatures from 278 to 343 K

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