Advances in clinkering technology of calcium sulfoaluminate cement

Isabel Galan Garcia; Ammar Elhoweris; Theodore Hanein; Marcus N Campbell Bannerman; Fredrik P Glasser

doi:10.1680/jadcr.17.00028

Advances in clinkering technology of calcium sulfoaluminate cement

Isabel Galan Garcia, Ammar Elhoweris, Theodore Hanein, Marcus N Campbell Bannerman, Fredrik P Glasser

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

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Abstract

A new method for producing calcium sulfoaluminate (CS̄A) clinkers is described. Sulfur is introduced from the gas phase as sulfur dioxide and oxygen and reacts with solids during clinkerisation. In this paper, the laboratory experiments are described and thermodynamic calculations are presented. The sulfur-containing phases ye'elimite and ternesite were stabilised together with belite to produce clinkers with various mineralogies. The influences of temperature and sulfur dioxide partial pressure were analysed and their effect on the formation of undesirable anhydrite and gehlenite was examined. The process by which a potentially hazardous waste material such as sulfur can be used as raw material, and possibly as fuel, to form CS̄A cements, is shown to be successful.

Original language	English
Pages (from-to)	405-417
Number of pages	13
Journal	Advances in Cement Research
Volume	29
Issue number	10
Early online date	19 Oct 2017
DOIs	https://doi.org/10.1680/jadcr.17.00028
Publication status	Published - Nov 2017

Bibliographical note

Acknowledgement
The authors gratefully acknowledge the financial support provided by the Gulf Organisation for Research and Development (GORD), Qatar, through University of Aberdeen research grant number ENG016RGG11757.

Funding Information: Gulf Organisation for Research and Development (GORD) (ENG016RGG11757)

Keywords

Clinkering/clinkering reactions
Special cements
Waste volarisation

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1680/jadcr.17.00028Licence: Unspecified

Accepted Draft
This is the author's manuscript as accepted for publication in Advances in Cement Research. http://www.icevirtuallibrary.com/toc/jadcr/current.
Accepted author manuscript, 2.9 MBLicence: Other

Marcus Campbell Bannerman
- Engineering, Engineering - Senior Lecturer
- Engineering, National Decommissioning Centre
Person: Academic

Cite this

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title = "Advances in clinkering technology of calcium sulfoaluminate cement",

abstract = "A new method for producing calcium sulfoaluminate (C{\=S}A) clinkers is described. Sulfur is introduced from the gas phase as sulfur dioxide and oxygen and reacts with solids during clinkerisation. In this paper, the laboratory experiments are described and thermodynamic calculations are presented. The sulfur-containing phases ye'elimite and ternesite were stabilised together with belite to produce clinkers with various mineralogies. The influences of temperature and sulfur dioxide partial pressure were analysed and their effect on the formation of undesirable anhydrite and gehlenite was examined. The process by which a potentially hazardous waste material such as sulfur can be used as raw material, and possibly as fuel, to form C{\=S}A cements, is shown to be successful.",

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author = "{Galan Garcia}, Isabel and Ammar Elhoweris and Theodore Hanein and {Campbell Bannerman}, {Marcus N} and Glasser, {Fredrik P}",

note = "Acknowledgement The authors gratefully acknowledge the financial support provided by the Gulf Organisation for Research and Development (GORD), Qatar, through University of Aberdeen research grant number ENG016RGG11757. Funding Information: Gulf Organisation for Research and Development (GORD) (ENG016RGG11757) ",

year = "2017",

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doi = "10.1680/jadcr.17.00028",

language = "English",

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pages = "405--417",

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T1 - Advances in clinkering technology of calcium sulfoaluminate cement

AU - Galan Garcia, Isabel

AU - Elhoweris, Ammar

AU - Hanein, Theodore

AU - Campbell Bannerman, Marcus N

AU - Glasser, Fredrik P

N1 - Acknowledgement The authors gratefully acknowledge the financial support provided by the Gulf Organisation for Research and Development (GORD), Qatar, through University of Aberdeen research grant number ENG016RGG11757. Funding Information: Gulf Organisation for Research and Development (GORD) (ENG016RGG11757)

PY - 2017/11

Y1 - 2017/11

N2 - A new method for producing calcium sulfoaluminate (CS̄A) clinkers is described. Sulfur is introduced from the gas phase as sulfur dioxide and oxygen and reacts with solids during clinkerisation. In this paper, the laboratory experiments are described and thermodynamic calculations are presented. The sulfur-containing phases ye'elimite and ternesite were stabilised together with belite to produce clinkers with various mineralogies. The influences of temperature and sulfur dioxide partial pressure were analysed and their effect on the formation of undesirable anhydrite and gehlenite was examined. The process by which a potentially hazardous waste material such as sulfur can be used as raw material, and possibly as fuel, to form CS̄A cements, is shown to be successful.

AB - A new method for producing calcium sulfoaluminate (CS̄A) clinkers is described. Sulfur is introduced from the gas phase as sulfur dioxide and oxygen and reacts with solids during clinkerisation. In this paper, the laboratory experiments are described and thermodynamic calculations are presented. The sulfur-containing phases ye'elimite and ternesite were stabilised together with belite to produce clinkers with various mineralogies. The influences of temperature and sulfur dioxide partial pressure were analysed and their effect on the formation of undesirable anhydrite and gehlenite was examined. The process by which a potentially hazardous waste material such as sulfur can be used as raw material, and possibly as fuel, to form CS̄A cements, is shown to be successful.

KW - Clinkering/clinkering reactions

KW - Special cements

KW - Waste volarisation

U2 - 10.1680/jadcr.17.00028

DO - 10.1680/jadcr.17.00028

M3 - Article

SN - 0951-7197

VL - 29

SP - 405

EP - 417

JO - Advances in Cement Research

JF - Advances in Cement Research

IS - 10

ER -

Advances in clinkering technology of calcium sulfoaluminate cement

Abstract

Bibliographical note

Keywords

UN SDGs

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Marcus Campbell Bannerman

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