Photochemical Fragmentation of Irgacure PAG 103

M. John Plater; William T. A. Harrison; Andrea Raab

doi:10.1021/acsomega.9b02621

Photochemical Fragmentation of Irgacure PAG 103

M. John Plater^* (Corresponding Author), William T. A. Harrison, Andrea Raab

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

6 Downloads (Pure)

Abstract

Photoisomerisation of Irgacure PAG 103 followed by photocyclisation and fragmentation leads to three tricyclic thieno[2,3-b]quinoline-4-carbonitrile heterocyclic compounds. The release of acid which can catalyse polymer resist modifications is indicated by the low pH of an aqueous extract. These reactions are discussed in view of possible mechanisms and how these might influence future design strategies.

Original language	English
Pages (from-to)	19875-19879
Number of pages	5
Journal	ACS Omega
Volume	4
Issue number	22
Early online date	12 Nov 2019
DOIs	https://doi.org/10.1021/acsomega.9b02621
Publication status	Published - 26 Nov 2019

Bibliographical note

Acknowledgments
We are grateful to BASF (Cheadle UK) for the donation of Irgacure PAG 103, the UK National Mass Spectrometry Service, and the UK National Crystallography Service.

Keywords

Irgacure PAG 103
chemical amplification
photoacid generator
oxime sulfonate
DESIGN
CHEMICAL AMPLIFICATION RESISTS
CONTAINED PHOTOACID GENERATOR
PHOTOCYCLIZATION
CATIONIC-POLYMERIZATION

Access to Document

10.1021/acsomega.9b02621Licence: Other

Plater_et_al_acsomega.PhotochemicalFragmentation_VoR
© 2019 American Chemical Society
Final published version, 732 KBLicence: Other

Cite this

@article{a2c414ef6b464e95b43758c3adff10ec,

title = "Photochemical Fragmentation of Irgacure PAG 103",

abstract = "Photoisomerisation of Irgacure PAG 103 followed by photocyclisation and fragmentation leads to three tricyclic thieno[2,3-b]quinoline-4-carbonitrile heterocyclic compounds. The release of acid which can catalyse polymer resist modifications is indicated by the low pH of an aqueous extract. These reactions are discussed in view of possible mechanisms and how these might influence future design strategies. ",

keywords = "Irgacure PAG 103, chemical amplification, photoacid generator, oxime sulfonate, DESIGN, CHEMICAL AMPLIFICATION RESISTS, CONTAINED PHOTOACID GENERATOR, PHOTOCYCLIZATION, CATIONIC-POLYMERIZATION",

author = "Plater, {M. John} and Harrison, {William T. A.} and Andrea Raab",

note = "Acknowledgments We are grateful to BASF (Cheadle UK) for the donation of Irgacure PAG 103, the UK National Mass Spectrometry Service, and the UK National Crystallography Service.",

year = "2019",

month = nov,

day = "26",

doi = "10.1021/acsomega.9b02621",

language = "English",

volume = "4",

pages = "19875--19879",

journal = "ACS Omega",

issn = "2470-1343",

publisher = "American Chemical Society",

number = "22",

}

TY - JOUR

T1 - Photochemical Fragmentation of Irgacure PAG 103

AU - Plater, M. John

AU - Harrison, William T. A.

AU - Raab, Andrea

N1 - Acknowledgments We are grateful to BASF (Cheadle UK) for the donation of Irgacure PAG 103, the UK National Mass Spectrometry Service, and the UK National Crystallography Service.

PY - 2019/11/26

Y1 - 2019/11/26

N2 - Photoisomerisation of Irgacure PAG 103 followed by photocyclisation and fragmentation leads to three tricyclic thieno[2,3-b]quinoline-4-carbonitrile heterocyclic compounds. The release of acid which can catalyse polymer resist modifications is indicated by the low pH of an aqueous extract. These reactions are discussed in view of possible mechanisms and how these might influence future design strategies.

AB - Photoisomerisation of Irgacure PAG 103 followed by photocyclisation and fragmentation leads to three tricyclic thieno[2,3-b]quinoline-4-carbonitrile heterocyclic compounds. The release of acid which can catalyse polymer resist modifications is indicated by the low pH of an aqueous extract. These reactions are discussed in view of possible mechanisms and how these might influence future design strategies.

KW - Irgacure PAG 103

KW - chemical amplification

KW - photoacid generator

KW - oxime sulfonate

KW - DESIGN

KW - CHEMICAL AMPLIFICATION RESISTS

KW - CONTAINED PHOTOACID GENERATOR

KW - PHOTOCYCLIZATION

KW - CATIONIC-POLYMERIZATION

UR - http://www.scopus.com/inward/record.url?scp=85075034204&partnerID=8YFLogxK

U2 - 10.1021/acsomega.9b02621

DO - 10.1021/acsomega.9b02621

M3 - Article

SN - 2470-1343

VL - 4

SP - 19875

EP - 19879

JO - ACS Omega

JF - ACS Omega

IS - 22

ER -

Photochemical Fragmentation of Irgacure PAG 103

Abstract

Bibliographical note

Keywords

Access to Document

Other files and links

Fingerprint

Michael Plater

Cite this

Photochemical Fragmentation of Irgacure PAG 103

Abstract

Bibliographical note

Keywords

Access to Document

Other files and links

Fingerprint

Profiles

Michael Plater

Cite this